Mixed-ligand copper complexes with unsymmetrical tridentate Schiff base ligands and 2,2′-bipyridine: Synthesis, x-ray crystallography and antibacterial properties

To investigate the effect of different halogen substituents, leaving groups and the flexibility of ligand on the anticancer activity of copper complexes, sixteen copper(II) complexes with eight different tridentate Schiff-base...

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Induced chirality-at-metal and diastereoselectivity at Δ/Λ-configured distorted square-planar copper complexes by enantiopure Schiff base ligands: combined circular dichroism, DFT and X-ray structural studies

Dalton Transactions ◽

10.1039/c3dt52871e ◽

2014 ◽

Vol 43 (8) ◽

pp. 3313-3329 ◽

Cited By ~ 41

Author(s):

Mohammed Enamullah ◽

A. K. M. Royhan Uddin ◽

Gennaro Pescitelli ◽

Roberto Berardozzi ◽

Gamall Makhloufi ◽

...

Keyword(s):

Schiff Base ◽

Circular Dichroism ◽

Copper Complexes ◽

Structural Studies ◽

Schiff Base Ligands ◽

X Ray ◽

Square Planar ◽

Circular Dichroïsm

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Oxo-rhenium(V) mixed-ligand complexes with bidentate functionalized phosphines and tridentate Schiff base ligands

Inorganica Chimica Acta ◽

10.1016/s0020-1693(01)00357-7 ◽

2001 ◽

Vol 315 (2) ◽

pp. 205-212 ◽

Cited By ~ 22

Author(s):

Cristina Bolzati ◽

Marina Porchia ◽

Giuliano Bandoli ◽

Alessandra Boschi ◽

Erica Malagò ◽

...

Keyword(s):

Schiff Base ◽

Mixed Ligand ◽

Mixed Ligand Complexes ◽

Schiff Base Ligands ◽

Tridentate Schiff Base

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Ligating properties of tridentate Schiff base ligands, 2-[[(2-pyridinylmethyl)imino]methyl] phenol (HSALIMP) and 2-[[[2-(2-pyridinyl)ethyl]imino]methyl]phenol (HSALIEP) with zinc(II), cadmium(II), nickel(II) and manganese(III) ions. X-ray crystal structures of the [Zn(SALIEP)(NO3)]2 dimer, [Mn(SALIEP)2](ClO4), and [Zn(AMP)2(NO3)2]

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)00010-4 ◽

2000 ◽

Vol 300-302 ◽

pp. 683-692 ◽

Cited By ~ 46

Author(s):

S.S Tandon ◽

S Chander ◽

L.K Thompson

Keyword(s):

Schiff Base ◽

Crystal Structures ◽

Schiff Base Ligands ◽

X Ray ◽

Tridentate Schiff Base

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Synthesis and characterization of two new N4O2 macroacyclic Schiff-base ligands containing piperazine moiety and mononuclear Co(III) and Cu(II) complexes, spectral, X-ray crystal structural, theoretical studies, cytotoxic and antibacterial properties

Polyhedron ◽

10.1016/j.poly.2017.03.035 ◽

2017 ◽

Vol 129 ◽

pp. 189-198 ◽

Cited By ~ 17

Author(s):

Hassan Keypour ◽

Masoumeh Mahmoudabadi ◽

Amir Shooshtari ◽

Mehdi Bayat ◽

Mitra Ghassemzadeh ◽

...

Keyword(s):

Schiff Base ◽

Antibacterial Properties ◽

Synthesis And Characterization ◽

Theoretical Studies ◽

Schiff Base Ligands ◽

X Ray ◽

Crystal Structural

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Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes

Canadian Journal of Chemistry ◽

10.1139/v04-110 ◽

2004 ◽

Vol 82 (9) ◽

pp. 1346-1352 ◽

Cited By ~ 5

Author(s):

Diane A Dickie ◽

Hanifa Jalali ◽

Rahul G Samant ◽

Michael C Jennings ◽

Jason AC Clyburne

Keyword(s):

Schiff Base ◽

Schiff Bases ◽

Structural Characterization ◽

Condensation Reaction ◽

Schiff Base Ligands ◽

X Ray ◽

X Ray Crystallography ◽

Aluminum Complexes

2,4,6-Triphenylbenzaldehyde 1 undergoes a condensation reaction with 2-aminophenol to give N-(2′,4′,6′-triphenylbenzylidene)-2-iminophenol (TPIP) 2. The imine 2 can be reduced with NaBH4 in ethanol to form N-(2′,4′,6′-triphenylbenzyl)-2-aminophenol (TPAP) 3. Addition of trimethylaluminum to 2 or 3 results in the formation of the complexes TPIP-AlMe2·AlMe3 (4) or TPAP-AlMe2 (5). Compounds 2, 3, and 4 have been crystallographically characterized.Key words: N,O ligands, aluminum, m-terphenyl, Schiff bases, X-ray crystallography.

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Structure and spectroscopy of uranyl salicylaldiminate complexes

Radiochimica Acta ◽

10.1524/ract.2013.2071 ◽

2013 ◽

Vol 101 (10) ◽

pp. 631-636 ◽

Cited By ~ 1

Author(s):

A. L. Tamasi ◽

C. L. Barnes ◽

J. R. Walensky

Keyword(s):

Schiff Base ◽

Nmr Spectroscopy ◽

Coordination Sphere ◽

Ancillary Ligand ◽

Schiff Base Ligands ◽

Uranyl Complexes ◽

X Ray ◽

X Ray Crystallography ◽

Chloride Ligand ◽

C Nmr

Summary The synthesis of uranyl complexes coordinated to tridentate, monoanionic salicylaldiminate (Schiff base) ligands was achieved by the reaction of UO2Cl2(THF)3, 1, with one equivalent of the corresponding sodium salicylaldiminate salts affording [(C9H6N)N=C(H)C6H2t Bu2O]UO2Cl(THF), 2, [(NC5H4)N=C(H)C6H2 t Bu2O]UO2Cl(THF), 3, and [(C6H4SCH3)N=C(H)C6H2tBu2O]UO2Cl(THF), 4. These are uncommon examples of uranyl complexes with a monoanionic ancillary ligand to stabilize the coordination sphere and one chloride ligand. Compounds 2-4 have been characterized by 1H and 13C NMR spectroscopy as well as IR and UVVis spectroscopy and their structures determined by X-ray crystallography.

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