Acridin-9(10H)-one-based blue thermally activated delayed fluorescence materials: improvement of color purity and efficiency stability

2022 ◽  
Vol 23 ◽  
pp. 100645
Author(s):  
Y. Mei ◽  
D. Liu ◽  
J. Li ◽  
R. Dong ◽  
M. Ma ◽  
...  
Author(s):  
Jia-Jun Hu ◽  
Xu-Feng Luo ◽  
Meng-Xi Mao ◽  
Hua-Xiu Ni ◽  
Xiao Liang ◽  
...  

Highly efficient multi-resonance thermally activated delayed fluorescence (MR-TADF) emitters with narrowband emissions based on B (boron)/ N (nitrogen) framework are crucial for next-generation full-color display with high color purity. This...


2021 ◽  
Vol 9 ◽  
Author(s):  
Ting Xu ◽  
Xiao Liang ◽  
Guohua Xie

There is a need to satisfy the high color purity requirement of display technology with a simply fabricated process. Herein, solution-processed blue thermally activated delayed fluorescence organic light-emitting diodes (OLEDs) with a narrow spectrum with a full width at half maximum (FWHM) of 32 nm and y color coordinate below 0.2 are demonstrated by employing a molecule containing boron and nitrogen atoms (TBN-TPA) as the guest emitter in the emissive layer. The opposite resonance positions of B-N atoms of TBN-TPA endows a multi-resonance effect, leading to high color purity.


2020 ◽  
Author(s):  
Masaki Saigo ◽  
Kiyoshi Miyata ◽  
Hajime Nakanotani ◽  
Chihaya Adachi ◽  
Ken Onda

We have investigated the solvent-dependence of structural changes along with intersystem crossing of a thermally activated delayed fluorescence (TADF) molecule, 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (o-3CzBN), in toluene, tetrahydrofuran, and acetonitrile solutions using time-resolved infrared (TR-IR) spectroscopy and DFT calculations. We found that the geometries of the S1 and T1 states are very similar in all solvents though the photophysical properties mostly depend on the solvent. In addition, the time-dependent DFT calculations based on these geometries suggested that the thermally activated delayed fluorescence process of o-3CzBN is governed more by the higher-lying excited states than by the structural changes in the excited states.<br>


2021 ◽  
Vol 12 (11) ◽  
pp. 1692-1699
Author(s):  
Ji Hye Lee ◽  
Jinhyo Hwang ◽  
Chai Won Kim ◽  
Amit Kumar Harit ◽  
Han Young Woo ◽  
...  

New polystyrene-based polymers with high π-extended hole transport pendants were synthesized to obtain a low turn-on voltage and high efficiency in solution-processed green TADF-OLEDs.


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