Sequential quartz purification of 125–63 µm material for in-situ cosmogenic nuclide analysis

Author(s):  
Ross J. Whitmore ◽  
Kevin P. Norton ◽  
Luisa Ashworth ◽  
Andrew N. Mackintosh
Keyword(s):  
2015 ◽  
Vol 26 ◽  
pp. 56-69 ◽  
Author(s):  
Nathaniel Lifton ◽  
Marc Caffee ◽  
Robert Finkel ◽  
Shasta Marrero ◽  
Kunihiko Nishiizumi ◽  
...  

2019 ◽  
Vol 13 (11) ◽  
pp. 2935-2951 ◽  
Author(s):  
Keir A. Nichols ◽  
Brent M. Goehring ◽  
Greg Balco ◽  
Joanne S. Johnson ◽  
Andrew S. Hein ◽  
...  

Abstract. We describe new Last Glacial Maximum (LGM) ice thickness constraints for three locations spanning the Weddell Sea Embayment (WSE) of Antarctica. Samples collected from the Shackleton Range, Pensacola Mountains, and the Lassiter Coast constrain the LGM thickness of the Slessor Glacier, Foundation Ice Stream, and grounded ice proximal to the modern Ronne Ice Shelf edge on the Antarctic Peninsula, respectively. Previous attempts to reconstruct LGM-to-present ice thickness changes around the WSE used measurements of long-lived cosmogenic nuclides, primarily 10Be. An absence of post-LGM apparent exposure ages at many sites led to LGM thickness reconstructions that were spatially highly variable and inconsistent with flow line modelling. Estimates for the contribution of the ice sheet occupying the WSE at the LGM to global sea level since deglaciation vary by an order of magnitude, from 1.4 to 14.1 m of sea level equivalent. Here we use a short-lived cosmogenic nuclide, in situ-produced 14C, which is less susceptible to inheritance problems than 10Be and other long-lived nuclides. We use in situ 14C to evaluate the possibility that sites with no post-LGM exposure ages are biased by cosmogenic nuclide inheritance due to surface preservation by cold-based ice and non-deposition of LGM-aged drift. Our measurements show that the Slessor Glacier was between 310 and up to 655 m thicker than present at the LGM. The Foundation Ice Stream was at least 800 m thicker, and ice on the Lassiter Coast was at least 385 m thicker than present at the LGM. With evidence for LGM thickening at all of our study sites, our in situ 14C measurements indicate that the long-lived nuclide measurements of previous studies were influenced by cosmogenic nuclide inheritance. Our inferred LGM configuration, which is primarily based on minimum ice thickness constraints and thus does not constrain an upper limit, indicates a relatively modest contribution to sea level rise since the LGM of < 4.6 m, and possibly as little as < 1.5 m.


2005 ◽  
Vol 239 (1-2) ◽  
pp. 140-161 ◽  
Author(s):  
Nathaniel A. Lifton ◽  
John W. Bieber ◽  
John M. Clem ◽  
Marc L. Duldig ◽  
Paul Evenson ◽  
...  

Radiocarbon ◽  
2004 ◽  
Vol 46 (1) ◽  
pp. 201-206 ◽  
Author(s):  
P Naysmith ◽  
G T Cook ◽  
W M Phillips ◽  
N A Lifton ◽  
R Anderson

Radiocarbon is produced within minerals at the earth's surface (in situ production) by a number of spallation reactions. Its relatively short half-life of 5730 yr provides us with a unique cosmogenic nuclide tool for the measurement of rapid erosion rates (>10−3 cm yr−1) and events occurring over the past 25 kyr. At SUERC, we have designed and built a vacuum system to extract 14C from quartz which is based on a system developed at the University of Arizona. This system uses resistance heating of samples to a temperature of approximately 1100° in the presence of lithium metaborate (LiBO2) to dissolve the quartz and liberate any carbon present. During extraction, the carbon is oxidized to CO2 in an O2 atmosphere so that it may be collected cryogenically. The CO2 is subsequently purified and converted to graphite for accelerator mass spectrometry (AMS) measurement. One of the biggest problems in measuring in situ 14C is establishing a low and reproducible system blank and efficient extraction of the in situ 14C component. Here, we present initial data for 14C-free CO2, derived from geological carbonate and added to the vacuum system to determine the system blank. Shielded quartz samples (which should be 14C free) and a surface quartz sample routinely analyzed at the University of Arizona were also analyzed at SUERC, and the data compared with values derived from the University of Arizona system.


2015 ◽  
Vol 26 ◽  
pp. 44-55 ◽  
Author(s):  
David C. Argento ◽  
John O. Stone ◽  
Robert C. Reedy ◽  
Keran O'Brien

2004 ◽  
Vol 61 (3) ◽  
pp. 335-338 ◽  
Author(s):  
Kevin Kiernan ◽  
L. Keith Fifield ◽  
John Chappell

Moraines on Schnells Ridge, southwest Tasmania, have been dated using in situ 10Be. An age of 19,400 ± 600 yr is indicated for the well-preserved innermost moraine from consistent measurements on four large quartzite boulders. This corresponds closely with exposure ages reported by T.T. Barrows et al. (2002, Quaternary Science Reviews 21, 159–173) for Last Glacial Maximum glacial features farther north in Tasmania and southeast Australia. In contrast, ages between 39,000 and 141,000 yr were obtained from a series of boulders on a more extensive outer moraine, indicating that this has had a more complex history.


Geochronology ◽  
2019 ◽  
Vol 1 (1) ◽  
pp. 43-52 ◽  
Author(s):  
Keir A. Nichols ◽  
Brent M. Goehring

Abstract. Froth flotation is a commonly used procedure for separating feldspars and micas from quartz for the preparation of quartz mineral separates to carry out cosmogenic nuclide analysis. Whilst extracting carbon from quartz we observed in situ carbon-14 (14C) concentrations which were anomalously high and in excess of theoretical geological maximum concentrations. Further etching of sample material reduced carbon yields and 14C concentrations, yet the latter remained unrealistically high. When quartz from the original whole rock sample was isolated in our laboratory, we observed even lower carbon yields and geologically plausible in situ 14C concentrations. After ruling out unlikely geological scenarios and systematic measurement issues, we decided to investigate the quartz isolation procedure as a potential source of 14C contamination. We hypothesised that laurylamine (dodecylamine), an organic compound used as part of the froth flotation procedure, elevates 14C concentrations if residual laurylamine is present. We demonstrate that laurylamine has a 14C modern carbon source and thus has the potential to influence in situ 14C measurements if present in minute but measurable quantities. Furthermore, we show that insufficient sample etching results in contaminant 14C persisting through the step heating of quartz that is subsequently collected with the in situ component released at 1100 ∘C. We demonstrate that froth flotation contaminates in situ 14C measurements. We provide guidelines for the preparation of quartz based on methods developed in our laboratory and demonstrate that all froth-flotation-derived carbon and 14C is removed when applied. We recommend that the procedures presented be used at a minimum when using froth flotation to isolate quartz for in situ 14C measurements.


2019 ◽  
Author(s):  
Keir A. Nichols ◽  
Brent M. Goehring ◽  
Greg Balco ◽  
Joanne S. Johnson ◽  
Andrew A. Hein ◽  
...  

Abstract. This paper describes new Last Glacial Maximum (LGM) ice thickness constraints for three locations spanning the Weddell Sea Embayment (WSE) of Antarctica. Samples collected from the Shackleton Range, Pensacola Mountains, and the Lassiter Coast constrain the LGM thickness of the Slessor Glacier, Foundation Ice Stream, and grounded ice proximal to the modern Ronne Ice Shelf Edge on the Antarctic Peninsula, respectively. Previous attempts to reconstruct LGM-to-present ice thickness changes around the WSE used measurements of long-lived cosmogenic nuclides, primarily 10Be. An absence of post-LGM apparent exposure ages at many sites led to LGM thickness reconstructions that were spatially highly variable, and inconsistent with flowline modeling. Estimates for the contribution of the ice sheet occupying the WSE at the LGM to global sea level since deglaciation vary by an order of magnitude, from 1.4 to 14.1 m of sea level equivalent. Here we use a cosmogenic nuclide, in situ produced 14C, to evaluate the possibility that sites with no post-LGM exposure ages are biased by cosmogenic nuclide inheritance due to surface preservation by cold-based ice and nondeposition of LGM-aged drift. Our measurements show that the Slessor Glacier was between 310 and 650 m thicker than present at the LGM. The Foundation Ice Stream was at least 800 m thicker, and ice on the Lassiter Coast was at least 385 m thicker than present at the LGM. With evidence for LGM thickening at all of our study sites, our in situ 14C measurements indicate that the long-lived nuclide measurements of previous studies were influenced by cosmogenic nuclide inheritance. Our LGM thickness constraints point toward a modest contribution from the Weddell Sea Embayment to global sea-level since deglaciation, with an estimated range of 2.2 to 5.8 m.


2021 ◽  
Author(s):  
◽  
Abby Jade Burdis

<p>New Zealand’s tectonically and climatically dynamic environment generates erosion rates that outstrip global averages by up to ten times in some locations. In order to assess recent changes in erosion rate, and also to predict future erosion dynamics, it is important to quantify long-term, background erosion. Current research on erosion in New Zealand predominantly covers short-term (100 yrs) erosion dynamics and Myr dynamics from thermochronological proxy data. Without competent medium-term denudation data for New Zealand, it is uncertain which variables (climate, anthropogenic disturbance of the landscape, tectonic uplift, lithological, or geomorphic characteristics) exert the dominant control on denudation in New Zealand. Spatially-averaged cosmogenic nuclide analysis can effectively offer this information by providing averaged rates of denudation on millennial timescales without the biases and limitations of short-term erosion methods.  Basin-averaged denudation rates were obtained in the Nelson/Tasman region, New Zealand, from analysis of concentrations of meteoric ¹⁰Be in silt and in-situ produced ¹⁰Be in quartz. The measured denudation rates integrate over ~2750 yrs (in-situ) and ~1200 yrs (meteoric). Not only do the ¹⁰Be records produce erosion rates that are remarkably consistent with each other, but they are also independent of topographic metrics. Denudation rates range from ~112 – 298 t km⁻² yr⁻¹, with the exception of one basin which is eroding at 600 - 800 t km⁻² yr⁻¹. The homogeneity of rates and absence of a significant correlation with geomorphic or lithological characteristics could indicate that the Nelson/Tasman landscape is in (or approaching) a topographic steady state.  Millennial term (¹⁰Be-derived) denudation rates are more rapid than those inferred from other conventional methods in the same region (~50 – 200 t km⁻² yr⁻¹). This is likely the result of the significant contribution of low frequency, high magnitude erosive events to overall erosion of the region. Both in-situ and meteoric ¹⁰Be analyses have the potential to provide competent millennial term estimates of natural background rates of erosion. This will allow for the assessment of geomorphic-scale impacts such as topography, tectonics, climate, and lithology on rates of denudation for the country where many conventional methods do not. Cosmogenic nuclides offer the ability to understand the response of the landscape to these factors in order to make confident erosion predictions for the future.</p>


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