Synthesis and characterization of the azido-bound five-coordinate high-spin iron(II) “picket fence” porphyrin complex

Polyhedron ◽  
2009 ◽  
Vol 28 (5) ◽  
pp. 954-958 ◽  
Author(s):  
Ibtissem Hachem ◽  
Mohamed Salah Belkhiria ◽  
Michel Giorgi ◽  
Charles E. Schulz ◽  
Habib Nasri
Keyword(s):  
High Spin ◽  
Synthesis And Characterization ◽  
Porphyrin Complex ◽  
Picket Fence ◽  
High Spin Iron

Synthesis and characterization of a modified “picket fence” porphyrin complex – stronger π bonding interactions between Fe(ii) and axial ligands

2015 ◽  
Vol 44 (30) ◽  
pp. 13651-13661 ◽  
Author(s):  
Baiyin He ◽  
Charles E. Schulz ◽  
Jianfeng Li
Keyword(s):  
New Species ◽  
Strong Correlation ◽  
Synthesis And Characterization ◽  
Porphyrin Complex ◽  
Axial Ligands ◽  
Picket Fence ◽  
A New Species

The synthesis and characterization of [Fe(MbenTpivPP)(1-MeIm)2], a new species among bis(imidazole) iron(ii) porphyrinates, is reported. Investigations suggest a strong correlation between mutual ligand orientations (θ) and axial Fe–NIm bond distances.

scholarly journals Synthesis and characterization of [7]triangulene

Nanoscale ◽  
2021 ◽  
Author(s):  
Shantanu Mishra ◽  
Kun Xu ◽  
Kristjan Eimre ◽  
Hartmut Komber ◽  
Ji Ma ◽  
...  
Keyword(s):  
High Spin ◽  
Ground States ◽  
Synthesis And Characterization ◽  
Spintronic Devices

Triangulene and its π-extended homologues constitute non-Kekulé polyradical frameworks with high-spin ground states, and are anticipated to be key components of organic spintronic devices. We report a combined in-solution and...

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