Effects of micelle structures formed in selective solvents on crystallization behaviors of poly(ethylene glycol)-b-poly(styrene) copolymers

Polymer ◽  
2007 ◽  
Vol 48 (9) ◽  
pp. 2755-2761 ◽  
Author(s):  
Yan-Feng Chen ◽  
Feng-Bo Zhang ◽  
Xu-Ming Xie ◽  
Jin-Ying Yuan
2010 ◽  
Vol 152-153 ◽  
pp. 1665-1668
Author(s):  
Lian Liu ◽  
Pei Wang ◽  
Chao Qu ◽  
Zhi Yong Wei ◽  
Min Qi

A family of poly(ethylene glycol)-b-poly(ε-caprolactone) (PEG-PCL) were synthesized in high yields by the ring-opening polymerization of monomethoxy-terminated poly(ethylene glycol) (mPEG) with ε-caprolactone in the presence of stannous octoate (Sn(Oct)2). Their crystallization behaviors were studied by DSC, XRD. The results illustrated that crystallization behaviors of the copolymers depended on the copolymer composition and the relative length of each block in copolymers. The melting peak of PCL block appeared gradually in the XRD patterns and DSC curves in copolymers, with increasing of the length of PCL blocks.


2019 ◽  
Vol 10 (10) ◽  
Author(s):  
Anton Bonartsev ◽  
Vera Voinova ◽  
Elizaveta Akoulina ◽  
Andrey Dudun ◽  
Irina Zharkova ◽  
...  

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