scholarly journals Parametric study of dry coating process of electrode particle with model material of sulfide solid electrolytes for all-solid-state battery

2017 ◽  
Vol 305 ◽  
pp. 241-249 ◽  
Author(s):  
Takashi Kawaguchi ◽  
Hideya Nakamura ◽  
Satoru Watano
Author(s):  
Roman Schlem ◽  
Ananya Banik ◽  
Saneyuki Ohni ◽  
Emmanuelle Suard ◽  
Wolfgang Zeier

The recent interest in the halide-based solid electrolytes Li<sub>3</sub>MX<sub>6</sub> (M = Y, Er, In; X = Cl, Br, I) shows these materials to be promising candidates for solid-state battery application, due to high ionic conductivity and large electrochemical stability window. However, almost nothing is known about the underlying lithium sub-structure within those compounds. Here, we investigate the lithium sub-structure of Li<sub>3</sub>YCl<sub>6</sub> and Li<sub>3</sub>YBr<sub>6</sub> using temperature-dependent neutron diffraction. We compare compounds prepared by classic solid-state syntheses with a mechanochemical synthesis to shed light on the influence of the synthetic approach on the reported yttrium disorder and the resulting surrounding lithium sub-structure. This work provides a better understanding of the strong differences in ionic transport depending on the synthesis procedure of Li<sub>3</sub>MX<sub>6</sub>.


2012 ◽  
Vol 1386 ◽  
Author(s):  
G. Sotiriou ◽  
S. Gass ◽  
S.E. Pratsinis

ABSTRACTDry-coated nanosilver is a promising material for bio-applications. Its inert and non-porous nanothin SiO2 coating preserves the plasmonic properties of the nanosilver and cures its toxicity by (1) preventing direct cell to silver contact and (2) blocking the release of toxic silver ions. However, fully hermetic coatings have, to date, not been produced. During the coating process, a certain number of core particles are either coated only partially, or escape the coating process entirely. Here, a systematic parametric study was undertaken in order to optimize an aerosol reactor for the synthesis and dry-coating of nanosilver. The reactor was optimized with respect to coating injection height, jet number, mixing flow rate. By synthesizing xAg/SiO2 composite particles, small silver sizes (9-11 nm) with relatively high Ag ion release were obtained. This enabled the quantitative evaluation of the coatings by Ag ion release measurements.


2020 ◽  
Vol 448 ◽  
pp. 227579 ◽  
Author(s):  
Hideya Nakamura ◽  
Takashi Kawaguchi ◽  
Tomoyuki Masuyama ◽  
Atsushi Sakuda ◽  
Toshiya Saito ◽  
...  

2020 ◽  
Author(s):  
Roman Schlem ◽  
Ananya Banik ◽  
Saneyuki Ohni ◽  
Emmanuelle Suard ◽  
Wolfgang Zeier

The recent interest in the halide-based solid electrolytes Li<sub>3</sub>MX<sub>6</sub> (M = Y, Er, In; X = Cl, Br, I) shows these materials to be promising candidates for solid-state battery application, due to high ionic conductivity and large electrochemical stability window. However, almost nothing is known about the underlying lithium sub-structure within those compounds. Here, we investigate the lithium sub-structure of Li<sub>3</sub>YCl<sub>6</sub> and Li<sub>3</sub>YBr<sub>6</sub> using temperature-dependent neutron diffraction. We compare compounds prepared by classic solid-state syntheses with a mechanochemical synthesis to shed light on the influence of the synthetic approach on the reported yttrium disorder and the resulting surrounding lithium sub-structure. This work provides a better understanding of the strong differences in ionic transport depending on the synthesis procedure of Li<sub>3</sub>MX<sub>6</sub>.


2017 ◽  
Vol 164 (12) ◽  
pp. A2474-A2478 ◽  
Author(s):  
Atsushi Sakuda ◽  
Kentaro Kuratani ◽  
Mari Yamamoto ◽  
Masanari Takahashi ◽  
Tomonari Takeuchi ◽  
...  

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