Synthesis, structural characterization, catalytic, thermal and electrochemical investigations of bidentate Schiff base ligand and its metal complexes

2010 ◽  
Vol 76 (2) ◽  
pp. 174-181 ◽  
Author(s):  
Mustafa Dolaz ◽  
Vickie McKee ◽  
Serhan Uruş ◽  
Necmettin Demir ◽  
Ali E. Sabik ◽  
...  
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Structural Characterization ◽  
Schiff Base Ligand ◽  
Bidentate Schiff Base Ligand

Metallkomplexe mit biologisch wichtigen Liganden, CXXXVII [1]. Halbsandwich-Komplexe mit N, O-Chelaten und Schiff-Basen von β-Aminosäuren/ Metal Complexes of Biologically Important Ligands, CXXXVII [1]. Halfsandwich Complexes with N, O-Chelates and Schiff Bases of β-Amino Acids

2001 ◽  
Vol 56 (4-5) ◽  
pp. 403-410 ◽  
Author(s):  
Daniela Koch ◽  
Winfried Hoffmüller ◽  
Kurt Polborn ◽  
Wolfgang Beck
Keyword(s):  
Amino Acids ◽  
Schiff Base ◽  
Metal Complexes ◽  
Ethyl Ester ◽  
Schiff Bases ◽  
Schiff Base Ligand ◽  
Schiff Base Complexes ◽  
Single Isomer ◽  
Bidentate Schiff Base Ligand

Abstract β-Phenylalanine forms with chloro bridged complexes the chiral N, O-chelates Cp*Ir(Cl)(NH2CH(Ph)CH2CO2) and (p-cymene)Ru(Cl)(NH2CHPhCH2CO2) as mixture of two diastereoisomers. Similarly the palladium(III) and platinum(II) complexes (Et3P)(Cl)M(NH2CH(Ph)CH2CO2) (M = Pd, Pt) were obtained. Schiff base complexes (arene)(Cl)M(O2CC(R)=N-CH(R)CH(R)CH2CO2CH3) (arene = Cp*, p-cymene; M = Ir, Ru) were synthesized from the chloro-bridged compounds, 2-oxocarboxylates and β-alanine or β-phenylalanine methylester. The Cp*Ir complex with a tridendate dianionic Schiff base generated from pyruvate and β-phenylalaninate is obtained as a single isomer. Cp*Ir(Cl) forms a complex with an N, O-bidentate Schiff base ligand from glycinate and acetylacetic ethyl ester.

scholarly journals Synthesis and Structural Characterization of Schiff Base Ligand and their Metal Complexes

2015 ◽  
Vol 32 (2) ◽  
pp. 1249-1254 ◽  
Author(s):  
Amit Gautam ◽  
Arun Kumar ◽  
Kaushlendra Sharma ◽  
B. K Rai
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Structural Characterization ◽  
Schiff Base Ligand
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