scholarly journals Synthesis, Characterization and Biological Application of Rhodium, Platinum and Gold Metal Complexes Derived from Bidentate Schiff Base Ligand (Research Article)

2021 ◽  
Vol 11 (1) ◽  
pp. 38-47
Author(s):  
Manik Rathod ◽  
Vijaykumar L. Chavan
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Schiff Base Ligand ◽  
Biological Application ◽  
Research Article ◽  
Bidentate Schiff Base Ligand ◽  
Gold Metal

Metallkomplexe mit biologisch wichtigen Liganden, CXXXVII [1]. Halbsandwich-Komplexe mit N, O-Chelaten und Schiff-Basen von β-Aminosäuren/ Metal Complexes of Biologically Important Ligands, CXXXVII [1]. Halfsandwich Complexes with N, O-Chelates and Schiff Bases of β-Amino Acids

2001 ◽  
Vol 56 (4-5) ◽  
pp. 403-410 ◽  
Author(s):  
Daniela Koch ◽  
Winfried Hoffmüller ◽  
Kurt Polborn ◽  
Wolfgang Beck
Keyword(s):  
Amino Acids ◽  
Schiff Base ◽  
Metal Complexes ◽  
Ethyl Ester ◽  
Schiff Bases ◽  
Schiff Base Ligand ◽  
Schiff Base Complexes ◽  
Single Isomer ◽  
Bidentate Schiff Base Ligand

Abstract β-Phenylalanine forms with chloro bridged complexes the chiral N, O-chelates Cp*Ir(Cl)(NH2CH(Ph)CH2CO2) and (p-cymene)Ru(Cl)(NH2CHPhCH2CO2) as mixture of two diastereoisomers. Similarly the palladium(III) and platinum(II) complexes (Et3P)(Cl)M(NH2CH(Ph)CH2CO2) (M = Pd, Pt) were obtained. Schiff base complexes (arene)(Cl)M(O2CC(R)=N-CH(R)CH(R)CH2CO2CH3) (arene = Cp*, p-cymene; M = Ir, Ru) were synthesized from the chloro-bridged compounds, 2-oxocarboxylates and β-alanine or β-phenylalanine methylester. The Cp*Ir complex with a tridendate dianionic Schiff base generated from pyruvate and β-phenylalaninate is obtained as a single isomer. Cp*Ir(Cl) forms a complex with an N, O-bidentate Schiff base ligand from glycinate and acetylacetic ethyl ester.

Synthesis, structures, and characterization of copper(II), nickel(II), and cobalt(III) metal complexes derived from an asymmetric bidentate Schiff-base ligand

2008 ◽  
Vol 61 (8) ◽  
pp. 1212-1220 ◽  
Author(s):  
Yanhong Song ◽  
Zhanwei Xu ◽  
Qingjin Sun ◽  
Biyun Su ◽  
Quanchang Gao ◽  
...  
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Schiff Base Ligand ◽  
Bidentate Schiff Base Ligand

DNA cleavage mechanism by metal complexes of Cu(II), Zn(II) and VO(IV) with a schiff-base ligand

Biochimie ◽  
2021 ◽  
Vol 186 ◽  
pp. 43-50
Author(s):  
María R. Rodríguez ◽  
Martín J. Lavecchia ◽  
Beatriz S. Parajón-Costa ◽  
Ana C. González-Baró ◽  
María R. González-Baró ◽  
...  
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Schiff Base Ligand ◽  
Dna Cleavage
Sign in / Sign up

Export Citation Format

Share Document