Synthesis, photophysical, quantum chemical investigation, linear and non-linear optical properties of coumarin derivative: Optoelectronic and optical limiting application

Author(s):  
A.G. Pramod ◽  
Y.F. Nadaf ◽  
C.G. Renuka
Author(s):  
FRYAD HENARI ◽  
ANDREW DAVEY ◽  
WERNER BLAU ◽  
P. HAISCH ◽  
M. HANACK

The valence electronic properties of some unsubstituted and peripherally substituted oxo-titanium phthalocyanines are reported. Semiempirical quantum chemical calculations show that the nature of peripheral substituents has a strong bearing on the valence electronic properties, including the state dipole moments and absorption wavelength. The non-linear optical response was measured around the the Q-band resonance. The effect of different substituents and substitution patterns on the non-linear behaviour of the samples was determined. The combined results suggest that tuning of electronic and optical properties is effectively achieved by functionalization of the edges of the conjugated ring.


2013 ◽  
Vol 67 (1) ◽  
Author(s):  
Alexandra Čibová ◽  
Peter Magdolen ◽  
Andrea Fülöpová ◽  
Pavol Zahradník

AbstractA series of novel monomethylated salts derived from linear benzobisthiazole was prepared. The push-pull attributes of these new compounds are represented by a quaternised azolium cycle as the acceptor part at one end of the structure and the dialkylamino- or diarylamino-substituted benzene ring as the donor part at the opposite end. Both moieties are connected by a conjugated linker consisting of one or two double bonds. Such dipolar structures are promising candidates for non-linear optical materials. The quantum-chemical indices describing linear and non-linear optical properties were obtained from semi-empirical calculations. The relationships between the chemical structure and non-linear optical properties of the cations studied were obtained. Effective conjugation was confirmed by measuring the optical properties in the UV-VIS region.


Carbon ◽  
2000 ◽  
Vol 38 (11-12) ◽  
pp. 1653-1662 ◽  
Author(s):  
Raffaella Signorini ◽  
Moreno Meneghetti ◽  
Renato Bozio ◽  
Michele Maggini ◽  
Gianfranco Scorrano ◽  
...  

2003 ◽  
Vol 771 ◽  
Author(s):  
C. Desroches ◽  
S. Parola ◽  
D. Cornu ◽  
P. Miele ◽  
P. L. Baldeck ◽  
...  

AbstractMacrocyclic thiacalixarenes have interesting non-linear optical properties. Thiacalixarenes bearing phenylazo, imino, ethynylic groups or platinum derived acetylides on the upper rims were designed, prepared and fully characterised. They showed interesting properties for optical limiting. Moreover these macrocycles are highly soluble in organic solvents and can easily be embedded in inorganic matrix using the sol-gel routes.Thiacalixarene based class I and II solid-state materials were prepared and their optical limiting behaviour was investigated.


2020 ◽  
Vol 30 (2) ◽  
pp. 335-346
Author(s):  
Chaitannya W. Ghanavatkar ◽  
Virendra R. Mishra ◽  
Suryapratap Sharma ◽  
Elizabeth Mathew ◽  
Subramaniyan Chitrambalam ◽  
...  

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