Mechanism and thermal rate constant for the gas-phase ozonolysis of acenaphthylene in the atmosphere

2015 ◽  
Vol 514 ◽  
pp. 344-350 ◽  
Author(s):  
Juan Dang ◽  
Xiangli Shi ◽  
Qingzhu Zhang ◽  
Jingtian Hu ◽  
Wenxing Wang
Keyword(s):  
Gas Phase ◽  
Rate Constant ◽  
Thermal Rate Constant

Reaction rate constant of SO3+ NH3in the gas phase

1990 ◽  
Vol 95 (D9) ◽  
pp. 13981 ◽  
Author(s):  
Gaunlin Shen ◽  
Masako Suto ◽  
L. C. Lee
Keyword(s):  
Gas Phase ◽  
Rate Constant ◽  
Reaction Rate ◽  
Reaction Rate Constant

scholarly journals Ruthenium trisbipyridine as a candidate for gas-phase spectroscopic studies in a Fourier transform mass spectrometer

2004 ◽  
Vol 18 (2) ◽  
pp. 387-396 ◽  
Author(s):  
Jill R. Scott ◽  
Jason E. Ham ◽  
Bill Durham ◽  
Paul L. Tremblay
Keyword(s):  
Fourier Transform ◽  
Gas Phase ◽  
Mass Spectrometer ◽  
Rate Constant ◽  
Optical Detection ◽  
Sinapinic Acid ◽  
Spectroscopic Studies ◽  
Fluorescence Lifetimes ◽  
Fourier Transform Mass Spectrometer

Metal polypyridines are excellent candidates for gas-phase optical experiments where their intrinsic properties can be studied without complications due to the presence of solvent. The fluorescence lifetimes of [Ru(bpy)3]1+trapped in an optical detection cell within a Fourier transform mass spectrometer were obtained using matrix-assisted laser desorption/ionization to generate the ions with either 2,5-dihydroxybenzoic acid (DHB) or sinapinic acid (SA) as matrix. All transients acquired, whether using DHB or SA for ion generation, were best described as approximately exponential decays. The rate constant for transients derived using DHB as matrix was 4×107s−1, while the rate constant using SA was 1×107s−1. Some suggestions of multiple exponential decay were evident although limited by the quality of the signals. Photodissociation experiments revealed that [Ru(bpy)3]1+generated using DHB can decompose to [Ru(bpy)2]1+, whereas ions generated using SA showed no decomposition. Comparison of the mass spectra with the fluorescence lifetimes illustrates the promise of incorporating optical detection with trapped ion mass spectrometry techniques.

Multivariate modelling of the rate constant of the gas-phase reaction of haloalkanes with the hydroxyl radical

1991 ◽  
Vol 109-110 ◽  
pp. 307-325 ◽  
Author(s):  
Maria Livia Tosato ◽  
Claudio Chiorboli ◽  
Lennart Eriksson ◽  
Jorgen Jonsson
Keyword(s):  
Hydroxyl Radical ◽  
Gas Phase ◽  
Rate Constant ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Multivariate Modelling
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