An yttria-doped ceria-based oxygen sensor with solid-state reference

ABSTRACTResistive type sensors using 10 mol% Hf-doped ceria and 10 mol% Zr-doped ceria, which had a single cubic phase obtained by solid state reaction, were fabricated and their sensing properties were investigated. The resistance and resistivity of the 10 mol% Hf-doped ceria or 10 mol% Zr-doped ceria were smaller than those of non-doped ceria. In the case of the same temperature of solid state reaction, the resistance and resistivity of the 10 mol% Hf-doped ceria were much smaller than those of the 10 mol% Zr-doped ceria. Furthermore, in the case of the same dopant, the resistance and resistivity of the sensor prepared from the solid state reaction at 1773 K were much smaller than those at 1673 K. The sensor using the 10 mol% Hf-doped ceria could be used as an oxygen gas sensor in wide oxygen partial pressure range and could be applicable to a λ sensor and a universal A/F sensor.

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Solid state compatibility between yttrium nickel manganite electrode and yttria-doped ceria and yttria-doped zirconia electrolytes

Solid State Ionics ◽

10.1016/s0167-2738(01)00965-1 ◽

2001 ◽

Vol 144 (3-4) ◽

pp. 257-262 ◽

Cited By ~ 2

Author(s):

C Moure

Keyword(s):

Solid State ◽

Doped Ceria ◽

Yttria Doped Ceria

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Potentiometric Oxygen Sensor with Solid State Reference Electrode

Metrology and Measurement Systems ◽

10.2478/mms-2014-0018 ◽

2014 ◽

Vol 21 (2) ◽

pp. 205-216 ◽

Cited By ~ 11

Author(s):

Katarzyna Dunst ◽

Grzegorz Jasinski ◽

Piotr Jasinski

Keyword(s):

Solid State ◽

Nickel Oxide ◽

Solid Electrolyte ◽

Oxygen Sensor ◽

Reference Electrode ◽

Oxide Mixture ◽

Oxygen Ion ◽

State Reference ◽

Ion Conducting ◽

Two Sides

Abstract The concentration or the partial pressure of oxygen in an environment can be determined using different measuring principles. For high temperature measurements of oxygen, ceramic-based sensors are the most practical. They are simple in construction, exploration and maintenance. A typical oxygen potentiometric sensor consists of an oxygen ion conducting solid electrolyte and two electrodes deposited on the two sides of the electrolyte. In this paper different structures of potentiometric oxygen sensors with a solid state reference electrode were fabricated and investigated. The fabricated structures consisted of oxygen ion conducting solid electrolyte from yttria stabilized zirconia, a sensing platinum electrode and nickel-nickel oxide reference electrode. The mixture of nickel-nickel oxide was selected as the reference electrode because it provides reliable electrochemical potential in contact with oxygen conducting electrolyte. To avoid oxidation of nickel the reference electrode is sealed from ambient and the mixture of nickel-nickel oxide was formed electrochemically from nickel oxide after sealing. The effectiveness of the sealing quality and the effectiveness of nickel-nickel oxide mixture formation was investigated by impedance spectroscopy.

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Analysis of solid state reaction at the interface of yttria-doped ceria/yttria-stabilized zirconia

Solid State Ionics ◽

10.1016/s0167-2738(98)00293-8 ◽

1998 ◽

Vol 113-115 (1-2) ◽

pp. 279-284 ◽

Cited By ~ 42

Author(s):

H Mitsuyasu

Keyword(s):

Solid State ◽

Solid State Reaction ◽

Yttria Stabilized Zirconia ◽

Doped Ceria ◽

Stabilized Zirconia ◽

Yttria Doped Ceria

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An experimental analysis of Thick-Film solid-state reference electrodes

2012 IEEE Sensors ◽

10.1109/icsens.2012.6411137 ◽

2012 ◽

Author(s):

M. Sophocleous ◽

M. Glanc-Gostkiewicz ◽

J. K. Atkinson ◽

E. Garcia-Breijo

Keyword(s):

Solid State ◽

Thick Film ◽

Experimental Analysis ◽

Reference Electrodes ◽

State Reference

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Vacancy and Cation Distribution in Yttria-Doped Ceria: An89Y and17O MAS NMR Study

Chemistry of Materials ◽

10.1021/cm0715388 ◽

2007 ◽

Vol 19 (23) ◽

pp. 5742-5747 ◽

Cited By ~ 59

Author(s):

Namjun Kim ◽

Jonathan F. Stebbins

Keyword(s):

Cation Distribution ◽

Mas Nmr ◽

Doped Ceria ◽

Nmr Study ◽

Yttria Doped Ceria

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Development and comparison of various rod-shaped mini-RE compositions based on Ag/AgCl for potentiometric applications

The Analyst ◽

10.1039/d1an01754c ◽

2022 ◽

Author(s):

Mustafa Nigde ◽

İsmail Ağır ◽

Rıdvan Yıldırım ◽

İbrahim Işıldak

Keyword(s):

Solid State ◽

Reference Electrode ◽

Reference Element ◽

State Reference

Several fundamentally similar, miniaturized solid-state reference electrode designs, their fabrication and comparison was described in this article. All electrodes were based on Ag/AgCl as their reference element. The best electrode...

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