A new paratungstate-A-based organic–inorganic hybrid compound: Synthesis, structure and photocatalytic property of [Co(en)3]2[H2W7O24]·8H2O

2013 ◽  
Vol 17 ◽  
pp. 146-150 ◽  
Author(s):  
Gang Yan ◽  
Xin Wang ◽  
Yuanyuan Ma ◽  
Xin Cheng ◽  
Yonghui Wang ◽  
...  
Keyword(s):  
Photocatalytic Property ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
Compound Synthesis

Synthesis, Structure Characterization and Photocatalytic Property of a New 3-D Polyoxovanadate-Based Organic-Inorganic Hybrid Compound

2014 ◽  
Vol 997 ◽  
pp. 260-263 ◽  
Author(s):  
Ya Bing Liu ◽  
Peng Yu
Keyword(s):  
Transition Metal ◽  
Elemental Analysis ◽  
Rhodamine B ◽  
Photocatalytic Property ◽  
Building Blocks ◽  
Structure Characterization ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
X Ray

A new polyoxovanadates-based organic-inorganic hybrid compound, [Cu(en)2]2[VV6VIV4O25] (1) has been hydrothermally synthesized and structurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 consists of [Cu(en)2]2+transition metal coordination fragment and the [VV6VIV4O25]4-building blocks, which are linked together via covalently-bonding interactions to form a new 3-D networks. The degradation of rhodamine B (RhB) under UV-vis irradiation with 1 as the heterogeneous photocatalyst has been investigated, showing a good photocatalytic property of 1 for RhB degradation.

Synthesis, Structure and Photocatalytic Property of [Ni(en)2]{[Ni(en)2]2[Mo8V8O40(VO4)]}[(NH2)2(C2H4)2NH]2·2H2O

2014 ◽  
Vol 1004-1005 ◽  
pp. 376-379
Author(s):  
Ya Bing Liu ◽  
Li Guang Xiao
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Property ◽  
Building Blocks ◽  
Chemical Formula ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
Inorganic Hybrid ◽  
X Ray ◽  
Metal Organic ◽  
Supramolecular Networks

A 1-D chain-like POM - based organic-inorganic hybrid compound with the chemical formula of [Ni (en)2]{[Ni (en)2]2[Mo8V8O40(VO4)]}[(NH2)2(C2H4)2NH]2·2H2O (en = ethylenediamine) (1) has been hydrothermally synthesized and structurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 consists of the bi-supported tetra-capped Keggin-type {[Ni (en)2]2[Mo8V8O40(VO4)]}2-building blocks and [Ni (en)2]2+metal organic cationic moieties are connected together to form 1-D chain through covelent-bonding interactions, which is further linked into 3-D supramolecular networks . The degradation of methylene blue (MB) under UV irradiation with 1 as the heterogeneous photocatalyst has been investigated, showing a good photocatalytic property of 1 for MB degradation.

A New POM-Based Supramolecular Compound: Synthesis, Structure and Adsorptive Property of [Cu(phen)2]3[W6O19]

2014 ◽  
Vol 919-921 ◽  
pp. 2013-2016 ◽  
Author(s):  
Ya Bing Liu ◽  
Hong Jie Wang ◽  
Hong Kai Zhao
Keyword(s):  
Three Dimensional ◽  
Building Blocks ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
Adsorptive Property ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Compound Synthesis ◽  
Metal Organic

A POM - based organice - inorganic hybrid compound with the chemical formula of[Cu (phen)2]3[W6O19] (phen = 1,10-phenanthroline) (1) has been hydrothermally synthesized andstructurally characterized by the elemental analysis, and single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic space groupC2/c witha=18.319(4) Å,b= 17.311(4) Å,c= 22.248(4) Å,β= 112.40(3) o,V= 6523(2) Å3,Z= 4, R1= 0.0448, andwR2=0.1218. Compound 1 consists of the [W6O19]3-building blocks and [Cu (phen)2]+metal organic cationic moieties, which are packed together via the extensive hydrogen-bonding interactions to form a three-dimensional supramolecular framework. The adsorption of methylene blue (MB) under UV irradiation with 1 as the heterogeneous adsorbent has been investigated, showing a good adsorptive property of 1 for MB degradation.

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