Preparation of PE-EPDM based phase change materials with great mechanical property, thermal conductivity and photo-thermal performance

2019 ◽  
Vol 200 ◽  
pp. 109988 ◽  
Author(s):  
Yanfeng Chen ◽  
Shiyuan Gao ◽  
Cuiyin Liu ◽  
Yue Situ ◽  
Jian Liu ◽  
...  
Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2230 ◽  
Author(s):  
Pumin Hou ◽  
Jinfeng Mao ◽  
Fei Chen ◽  
Yong Li ◽  
Xian Dong

In this paper, a series of Na2SO4·10H2O–KCl eutectic mixtures were prepared by adding different mass fractions of KCl (1 wt.%, 3 wt.%, 5 wt.%, or 7 wt.%) to Na2SO4·10H2O. Polyacrylamide (PAM) was proposed as the thickener, sodium tetraborate decahydrate (STD) was proposed as the nucleating agent, and expanded graphite (EG) was proposed as the high thermal conductivity medium for Na2SO4·10H2O–5 wt.% KCl eutectics. The results showed that in Na2SO4·10H2O–5 wt.% KCl eutectics with 5 wt.% PAM and 5 wt.% STD, almost no phase separation occurred, and the degree of supercooling was reduced to 0.4 °C. The thermal performance of Na2SO4·10H2O–5 wt.% KCl composite phase change materials (CPCMs) with varying contents of EG was explored. The results showed that EG could improve the thermal conductivity effectively and that the mass fraction of EG should be no more than 3%, otherwise the crystallization value and supercooling would deteriorate. The thermal reliability of the Na2SO4·10H2O–5 wt.% KCl eutectic CPCMs containing 5 wt.% PAM, 5 wt.% STD, and 3 wt.% EG was investigated, mainly through the ambient temperature, thermal cycling test, and TGA analysis. The results demonstrated that these CPCMs showed perfect thermal reliability.


Author(s):  
Fuxian Wang ◽  
Xuelin Zou ◽  
Yanfeng Chen ◽  
Jian Liu

Traditional phase change composites usually suffer poor mechanical property and easy collapsing in the phase changing process. Herein, a highly flexible phase change composite is fabricated using thermoplastic elastomer as the basic gel and the expanded graphite/paraffin as the filler. This new phase change composite shows a tensile strength of 2.1 MPa and a breaking elongation of 220%. It has a melting enthalpy of 145.4 J•g-1 and a thermal conductivity of 2.2 W•m-1•K-1 with 70% of expanded graphite/paraffin. The thermoplastic elastomer based phase change composite exhibits great reversible property after 200 heating/cooling cycles. This flexible phase change composite demonstrates good photo-thermal energy charging/discharging property and shows great potential to be applied in the solar thermal energy systems.


2021 ◽  
Vol 2116 (1) ◽  
pp. 012058
Author(s):  
M Silvestrini ◽  
M Falcone ◽  
F Salvi ◽  
C Naldi ◽  
M Dongellini ◽  
...  

Abstract The thermal performance of latent heat thermal energy storage (LHTES) systems considerably depends on thermal conductivity of adopted phase change materials (PCMs). To increase the low thermal conductivity of these materials, pure PCMs can be loaded with metal foams. In this study, the melting process of pure and metal-foam loaded phase change materials placed in a rectangular shape case is experimentally investigated by imposing a constant heat flux at the top. Two different paraffin waxes with melting point of about 35°C are tested. The results obtained with pure PCM are compared with those achieved from the use of PCM combined with two different porous metals: a 10 PPI aluminum foam with 96% porosity and a 20 PPI copper foam with 95% porosity. The results demonstrate how metal foams lead to a significant improvement of conduction heat transfer reducing significantly the melting time and the temperature difference between the heater and PCM.


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