scholarly journals Emergence of low-energy electronic states in oxygen-controlled Mott insulator Ca2RuO4+δ

2020 ◽  
pp. 114180
Author(s):  
Takeo Miyashita ◽  
Hideaki Iwasawa ◽  
Tomoki Yoshikawa ◽  
Shusuke Ozawa ◽  
Hironoshin Oda ◽  
...  
1992 ◽  
Vol 45 (17) ◽  
pp. 10032-10050 ◽  
Author(s):  
Mark S. Hybertsen ◽  
E. B. Stechel ◽  
W. M. C. Foulkes ◽  
M. Schlüter

2022 ◽  
Vol 130 (1) ◽  
pp. 121
Author(s):  
В.И. Царюк ◽  
К.П. Журавлев

The luminescence excitation energy transfer in europium and terbium indole-3-carboxylates, indole-3-acetates and indole-3-propionates as well as ternary indolecarboxylates containing 1,10-phenanthroline and 2,2'-bipyridine molecules have been studied. The luminescence excitation spectra, the lifetimes of the 5D0 (Eu3+) and 5D4 (Tb3+) states, and the luminescence intensity are analyzed. The decisive role of ligand-metal charge transfer (LMCT) states in the quenching of the luminescence of europium aromatic carboxylates containing a π-excessive pyrrole or indole fragment is demonstrated. Most europium compounds are characterized by quenching due to the depopulation of the 5D0 state of the Eu3+ ion through the low-energy LMCT state. But in some ternary compounds, the LMCT state being of higher energy participates in the nonradiative depopulation of the excited electronic states of the ligand.


1998 ◽  
Vol 118 (12) ◽  
pp. 1347-1354 ◽  
Author(s):  
Daisuke Fujita ◽  
Naoki Nakanishi ◽  
Kazuya Tada ◽  
Mitsuyoshi Onoda ◽  
Hiroshi Nakayama

2019 ◽  
Vol 12 (5) ◽  
pp. 051009 ◽  
Author(s):  
Soichiro Yamanaka ◽  
Ko Tonami ◽  
Masaki Iwashita ◽  
Koki Yoshida ◽  
Riku Takeuchi ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document