Pt-based anode catalysts for direct ethanol fuel cells

2004 ◽  
Vol 175 (1-4) ◽  
pp. 797-803 ◽  
Author(s):  
W ZHOU
Author(s):  
Tai Thien Huynh ◽  
Nam Nguyen Dang ◽  
Hau Quoc Pham

Elevating the electrocatalytic performance of both cathode and anode catalysts is critical to the advancement and widespread utilization of low-temperature fuel cells.


2004 ◽  
Vol 131 (1-2) ◽  
pp. 217-223 ◽  
Author(s):  
W.J. Zhou ◽  
W.Z. Li ◽  
S.Q. Song ◽  
Z.H. Zhou ◽  
L.H. Jiang ◽  
...  

2014 ◽  
Vol 39 (28) ◽  
pp. 15907-15912 ◽  
Author(s):  
Yumi Oh ◽  
Sang-Kyung Kim ◽  
Dong-Hyun Peck ◽  
Jin-sung Jang ◽  
Jiyoung Kim ◽  
...  

ChemSusChem ◽  
2009 ◽  
Vol 2 (2) ◽  
pp. 171-176 ◽  
Author(s):  
Daobao Chu ◽  
Shuxi Wang ◽  
Peng Zheng ◽  
Jian Wang ◽  
Longwu Zha ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 166 ◽  
Author(s):  
Yun Zheng ◽  
Xiaojuan Wan ◽  
Xin Cheng ◽  
Kun Cheng ◽  
Zhengfei Dai ◽  
...  

Direct ethanol fuel cells (DEFCs) have emerged as promising and advanced power systems that can considerably reduce fossil fuel dependence, and thus have attracted worldwide attention. DEFCs have many apparent merits over the analogous devices fed with hydrogen or methanol. As the key constituents, the catalysts for both cathodes and anodes usually face some problems (such as high cost, low conversion efficiency, and inferior durability) that hinder the commercialization of DEFCs. This review mainly focuses on the most recent advances in nanostructured catalysts for anode materials in DEFCS. First, we summarize the effective strategies used to achieve highly active Pt- and Pd-based catalysts for ethanol electro-oxidation, including composition control, microstructure design, and the optimization of support materials. Second, a few non-precious catalysts based on transition metals (such as Fe, Co, and Ni) are introduced. Finally, we outline the concerns and future development of anode catalysts for DEFCs. This review provides a comprehensive understanding of anode catalysts for ethanol oxidation in DEFCs.


2021 ◽  
Vol 22 (4) ◽  
pp. 1740 ◽  
Author(s):  
Selestina Gorgieva ◽  
Azra Osmić ◽  
Silvo Hribernik ◽  
Mojca Božič ◽  
Jurij Svete ◽  
...  

Herein, we prepared a series of nanocomposite membranes based on chitosan (CS) and three compositionally and structurally different N-doped graphene derivatives. Two-dimensional (2D) and quasi 1D N-doped reduced graphene oxides (N-rGO) and nanoribbons (N-rGONRs), as well as 3D porous N-doped graphitic polyenaminone particles (N-pEAO), were synthesized and characterized fully to confirm their graphitic structure, morphology, and nitrogen (pyridinic, pyrrolic, and quaternary or graphitic) group contents. The largest (0.07%) loading of N-doped graphene derivatives impacted the morphology of the CS membrane significantly, reducing the crystallinity, tensile properties, and the KOH uptake, and increasing (by almost 10-fold) the ethanol permeability. Within direct alkaline ethanol test cells, it was found that CS/N rGONRs (0.07 %) membrane (Pmax. = 3.7 mWcm−2) outperformed the pristine CS membrane significantly (Pmax. = 2.2 mWcm−2), suggesting the potential of the newly proposed membranes for application in direct ethanol fuel cells.


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