Subcritical water electrolysis for cobalt recovery from spent lithium-ion batteries in an acidic environment

2022 ◽  
Vol 181 ◽  
pp. 105501
Author(s):  
Wahyudiono ◽  
Kosuke Kosugi ◽  
Rumiko Hayashi ◽  
Siti Machmudah ◽  
Rodolfo Morales Ibarra ◽  
...  
2019 ◽  
Vol 36 (5) ◽  
pp. 908-914
Author(s):  
Yueshan Yu ◽  
Dahui Wang ◽  
Huaijing Chen ◽  
Xiaodong Zhang ◽  
Li Xu ◽  
...  

2012 ◽  
Vol 37 (22) ◽  
pp. 16795-16799 ◽  
Author(s):  
Eric M. Garcia ◽  
Vanessa de Freitas C. Lins ◽  
Hosane A. Tarôco ◽  
Tulio Matencio ◽  
Rosana Z. Domingues ◽  
...  

2015 ◽  
Vol 93 (12) ◽  
pp. 2198-2204 ◽  
Author(s):  
Jeanine Muller da Cunha ◽  
Laura Klein ◽  
Mariana Moro Bassaco ◽  
Eduardo Hiromitsu Tanabe ◽  
Daniel Assumpção Bertuol ◽  
...  

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2166 ◽  
Author(s):  
Jenni Lie ◽  
Stefani Tanda ◽  
Jhy-Chern Liu

The leaching of valuable metals (Co, Li, and Mn) from spent lithium-ion batteries (LIBs) was studied using subcritical water extraction (SWE). Two types of leaching agents, hydrochloric acid (HCl) and ascorbic acid, were used, and the effects of acid concentration and temperature were investigated. Leaching efficiency of metals increased with increasing acid concentration and temperature. Ascorbic acid performed better than HCl, which was attributed to ascorbic acid’s dual functions as an acidic leaching agent and a reducing agent that facilitates leaching reactions, while HCl mainly provides acidity. The chemical analysis of leaching residue by X-ray photoelectron spectroscopy (XPS) revealed that Co(III) oxide could be totally leached out in ascorbic acid but not in HCl. More than 95% of Co, Li, and Mn were leached out from spent LIBs’ cathode powder by SWE using 0.2 M of ascorbic acid within 30 min at 100 °C, initial pressure of 10 bar, and solid-to-liquid ratio of 10 g/L. The application of SWE with a mild concentration of ascorbic acid at 100 °C could be an alternative process for the recovery of valuable metal in spent LIBs. The process has the advantages of rapid reaction rate and energy efficiency that may benefit development of a circular economy.


Author(s):  
Shaohua Lu ◽  
Weidong Hu ◽  
Xiaojun Hu

Due to their low cost and improved safety compared to lithium-ion batteries, sodium-ion batteries have attracted worldwide attention in recent decades.


Author(s):  
А.Б. Абдрахманова ◽  
◽  
В. А. Кривченко ◽  
Н. М. Омарова

2017 ◽  
Vol 137 (8) ◽  
pp. 481-486
Author(s):  
Junichi Hayasaka ◽  
Kiwamu Shirakawa ◽  
Nobukiyo Kobayashi ◽  
Kenichi Arai ◽  
Nobuaki Otake ◽  
...  

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