Influence of pore structure on ion diffusion property in porous TiO2 coating and photovoltaic performance of dye-sensitized solar cells

2011 ◽  
Vol 205 (10) ◽  
pp. 3205-3210 ◽  
Author(s):  
Guan-Jun Yang ◽  
Chang-Jiu Li ◽  
Sheng-Qiang Fan ◽  
Jin-Cheng Gao
2011 ◽  
Vol 418-420 ◽  
pp. 1847-1850
Author(s):  
Ya Fang Tian ◽  
Zeng Chen ◽  
Sheng Jun Li

In this paper, we investigated the diffusion behaviour of in the mixture of ethylene carbonate (EC) and propylene carbonate (PC) electrolyte solidified by polyacrylonitrile ( PAN, molecular weight: 60,000). The effect of the ion diffusion process on the photoelectric properties was also studied. The ion diffusion process was found to be the main factor to the photoelectric properties in the quasi-solid state dye-sensitized solar cells. Some ideas, such as the optimization of the thickness and the concentration of in the electrolyte, were proposed to improve the transport velocity of.


2020 ◽  
Vol 44 (30) ◽  
pp. 12909-12915
Author(s):  
Yi-Qiao Yan ◽  
Yi-Zhou Zhu ◽  
Pan-Pan Dai ◽  
Jun Han ◽  
Mao Yan ◽  
...  

Effects of hetero-donors on the photovoltaic performance of tetraphenylethylene-based organic dyes were systematically investigated.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2150
Author(s):  
Ji-Hye Kim ◽  
Sung-Yoon Park ◽  
Dong-Hyuk Lim ◽  
So-Young Lim ◽  
Jonghoon Choi ◽  
...  

Organic solvents used for electrolytes of dye-sensitized solar cells (DSSCs) are generally not only toxic and explosive but also prone to leakage due to volatility and low surface tension. The representative dyes of DSSCs are ruthenium-complex molecules, which are expensive and require a complicated synthesis process. In this paper, the eco-friendly DSSCs were presented based on water-based electrolytes and a commercially available organic dye. The effect of aging time after the device fabrication and the electrolyte composition on the photovoltaic performance of the eco-friendly DSSCs were investigated. Plasma treatment of TiO2 was adopted to improve the dye adsorption as well as the wettability of the water-based electrolytes on TiO2. It turned out that the plasma treatment was an effective way of improving the photovoltaic performance of the eco-friendly DSSCs by increasing the efficiency by 3.4 times. For more eco-friendly DSSCs, the organic-synthetic dye was replaced by chlorophyll extracted from spinach. With the plasma treatment, the efficiency of the eco-friendly DSSCs based on water-electrolytes and chlorophyll was comparable to those of the previously reported chlorophyll-based DSSCs with non-aqueous electrolytes.


Molecules ◽  
2020 ◽  
Vol 25 (1) ◽  
pp. 198 ◽  
Author(s):  
Michèle Chevrier ◽  
Alberto Fattori ◽  
Laurent Lasser ◽  
Clément Kotras ◽  
Clémence Rose ◽  
...  

Chlorophyll a derivatives were integrated in “all solid-state” dye sensitized solar cells (DSSCs) with a mesoporous TiO2 electrode and 2′,2′,7,7′-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene as the hole-transport material. Despite modest power conversion efficiencies (PCEs) between 0.26% and 0.55% achieved for these chlorin dyes, a systematic investigation was carried out in order to elucidate their main limitations. To provide a comprehensive understanding of the parameters (structure, nature of the anchoring group, adsorption …) and their relationship with the PCEs, density functional theory (DFT) calculations, optical and photovoltaic studies and electron paramagnetic resonance analysis exploiting the 4-carboxy-TEMPO spin probe were combined. The recombination kinetics, the frontier molecular orbitals of these DSSCs and the adsorption efficiency onto the TiO2 surface were found to be the key parameters that govern their photovoltaic response.


2012 ◽  
Vol 4 (10) ◽  
pp. 5287-5292 ◽  
Author(s):  
Sun Hye Hwang ◽  
Chanhoi Kim ◽  
Hee Song ◽  
Suim Son ◽  
Jyongsik Jang

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