Local and non-local properties controlling the strength of Brønsted acids and bases

2007 ◽  
Vol 810 (1-3) ◽  
pp. 121-128 ◽  
Author(s):  
G.F. Cerofolini ◽  
A. Marrone ◽  
N. Re
2020 ◽  
Vol 63 (1) ◽  
pp. 116-135
Author(s):  
Anton V. Kuznetsov

The articles examines the teleofunctional solution to the problem of mental causation, presented by Dmitry Volkov in his recently published book Free Will. An Illusion or an Opportunity. D.B. Volkov proposes solutions to three big metaphysical problems – mental causation, personal identity, and free will. Solving the first problem, Volkov creatively combines the advantages of Dennett’s teleofunctional model and Vasilyev’s local interactionism. Volkov’s teleofunctional model of mental causation seeks to prove the causal relevance of mental properties as non-local higher order properties. In my view, its substantiation is based on three points: (a) critics of the exclusion problem and Kim’s model of mental causation, (b) “Library of first editions” argument, (c) reduction of the causal trajectories argument (CTA 1) by Vasilyev to the counterpart argument (CTA 2) by Volkov. Each of these points faces objections. Kim’s criticism is based on an implicit confusion of two types of reduction – reduction from supervenience and from multiple realizability. The latter type does not threaten Kim’s ideas, but Volkov uses this very type in his criticism. The “Library of first editions” argument does not achieve its goal due to compositional features and because non-local relational properties are a type of external properties that cannot be causally relevant. The reduction of CTA 1 to CTA 2 is unsuccessful since, in the case of this reduction, important features of CTA 1 are lost – these are local mental properties, due to which the influence of non-local physical factors occurs. My main objection is that the concept of causally relevant non-local properties is incompatible with the very concept of cause. The set of causally relevant properties of cause can only be local.


2020 ◽  
Vol 498 (2) ◽  
pp. 2663-2675
Author(s):  
Federico Tosone ◽  
Mark C Neyrinck ◽  
Benjamin R Granett ◽  
Luigi Guzzo ◽  
Nicola Vittorio

ABSTRACT We present a public code to generate random fields with an arbitrary probability distribution function (PDF) and an arbitrary correlation function. The algorithm is cosmology independent and applicable to any stationary stochastic process over a three-dimensional grid. We implement it in the case of the matter density field, showing its benefits over the lognormal approximation, which is often used in cosmology for the generation of mock catalogues. We find that the covariance of the power spectrum from the new fast realizations is more accurate than that from a lognormal model. As a proof of concept, we also apply the new simulation scheme to the divergence of the Lagrangian displacement field. We find that information from the correlation function and the PDF of the displacement–divergence provides modest improvement over other standard analytical techniques to describe the particle field in the simulation. This suggests that further progress in this direction should come from multiscale or non-local properties of the initial matter distribution.


2013 ◽  
Vol 15 (41) ◽  
pp. 17971
Author(s):  
Ilmar A. Koppel ◽  
Peeter Burk ◽  
Kalev Kasemets ◽  
Ivar Koppel

Author(s):  
B.A. Lyashenko ◽  
Z.A. Stotsko ◽  
O.A. Kuzin ◽  
M.O. Kuzin

Purpose: The purpose of this work is to build new computational schemes for assessing the strength parameters of parts with inhomogeneous properties of surface layers in the presence of stress concentrators. Design/methodology/approach: Using the developed approaches of mathematical modeling and open software for calculating the structures of the FEM - FEniCS, the required thickness of the hardened zones of parts has been established, which ensures their minimum softening during operation, depending on the characteristics of the stress concentrator. Findings: It is shown that for each size of the surface stress concentrator there is a critical value of the hardening thickness, the excess of which does not affect the operational strength of the parts, but increases the cost of technological operations. Research limitations/implications: In this article proposes a method for calculating the influence of the dimensional characteristics of hardening zones on the contact strength of parts with stress concentrators under conditions of prevailing power loads. Practical implications: The results obtained in this work were used to determine the technological modes of plasma hardening, which ensure an increase in the contact strength of parts with stress concentrators, depending on their dimensional characteristics. Originality/value: Using the approaches of computational mechanics and mathematical and computer modeling, methods for controlling the contact strength of parts with inhomogeneous non-local properties in the presence of a surface stress concentrator are proposed for the first time.


Sign in / Sign up

Export Citation Format

Share Document