Glassy carbon electrode coated with polyaniline-functionalized carbon nanotubes for detection of trace lead in acetate solution

2011 ◽  
Vol 519 (15) ◽  
pp. 5280-5284 ◽  
Author(s):  
Zhaomeng Wang ◽  
Erjia Liu ◽  
Donghao Gu ◽  
Yongsheng Wang
Keyword(s):  
Carbon Nanotubes ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Carbon Electrode ◽  
Acetate Solution ◽  
Functionalized Carbon Nanotubes

scholarly journals Differential pulse adsorptive stripping voltammetric determination of methotrexate using a functionalized carbon nanotubes-modified glassy carbon electrode

2013 ◽  
Vol 11 (11) ◽  
pp. 1837-1843 ◽  
Author(s):  
Geiser Oliveira ◽  
Bruno Janegitz ◽  
Valtencir Zucolotto ◽  
Orlando Fatibello-Filho
Keyword(s):  
Carbon Nanotubes ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
High Performance ◽  
Comparative Method ◽  
Differential Pulse ◽  
Carbon Electrode ◽  
Experimental Conditions ◽  
Functionalized Carbon Nanotubes

AbstractA glassy carbon electrode (GC) containing multiwalled functionalized carbon nanotubes (MWCNTs) immobilized within a dihexadecylhydrogenphosphate film (DHP) is proposed as a nanostructured platform for determination of methotrexate (MTX) concentration (a drug used in cancer treatment) using differential pulse adsorptive stripping voltammetry (DPAdSV). The voltammograms for a MTX solution using MWCNTs-DHP/GC electrode presented an oxidation peak potential at 0.98 V vs. Ag/AgCl (3.0 mol L−1 KCl) in a 0.1 mol L−1 sulphuric acid. The apparent heterogeneous electron transfer rate constant of 0.46 s−1 was calculated. The recovery area of 2.62×10−9 mol cm2 was also obtained. Under the optimal experimental conditions, the analytical curve was linear in the MTX concentration range from 5.0×10−8 to 5.0×10−6 mol L−1, with a detection limit of 3.3×10−8 mol L−1. The MWCNTs-DHP/GC electrode can be easily prepared and was applied for the determination of MTX in pharmaceutical formulations, with results similar to those obtained using a high-performance liquid chromatography comparative method.

scholarly journals Electrochemical Determination of Capsaicinoids Content in Soy Sauce and Pot-Roast Meat Products Based on Glassy Carbon Electrode Modified with Β-Cyclodextrin/Carboxylated Multi-Wall Carbon Nanotubes

Foods ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 1743
Author(s):  
Qianhui Gu ◽  
Chaoqun Lu ◽  
Kangwen Chen ◽  
Xingguang Chen ◽  
Pengfei Ma ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrochemical Sensor ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Meat Products ◽  
Soy Sauce ◽  
Relative Dispersion ◽  
Carbon Electrode ◽  
Trace Detection ◽  
Multi Wall Carbon Nanotubes

The rapid quantification of capsaicinoids content is very important for the standardization of pungent taste degree and flavor control of soy sauce and pot-roast meat products. To rapidly quantify the capsaicinoids content in soy sauce and pot-roast meat products, an electrochemical sensor based on β-cyclodextrin/carboxylated multi-wall carbon nanotubes was constructed and the adsorptive stripping voltammetry method was used to enrich samples in this study. The results showed that the excellent performance of the established electrochemical sensor was mostly because β-cyclodextrin caused the relative dispersion of carboxylated multi-wall carbon nanotubes on the glassy carbon electrode surface. Capsaicin and dihydrocapsaicin had similar electrochemical behavior, so the proposed method could determine the total content of capsaicinoids. The linearity of capsaicinoids content was from 0.5 to 100 μmol/L and the detection limit was 0.27 μmol/L. The recovery rates of different capsaicinoids content were between 83.20% and 136.26%, indicating the proposed sensor could realize trace detection of capsaicinoids content in sauce and pot-roast meat products. This work provides a research basis for pungent taste degree standardization and flavor control in the food industry.

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