Influence of sodium aluminate on calcium leaching of shotcrete in tunnels

2021 ◽  
Vol 117 ◽  
pp. 104156
Author(s):  
Fei Ye ◽  
Biao He ◽  
Chong-ming Tian ◽  
Meng Zhao ◽  
Jian Wang ◽  
...  
Keyword(s):  
Sodium Aluminate ◽  
Calcium Leaching

A transmission electron microscopic study of structural transitions in fast ionic conductors

1987 ◽  
Vol 45 ◽  
pp. 156-157
Author(s):  
R. B. Queenan ◽  
P. K. Davies
Keyword(s):  
Optical Properties ◽  
Ionic Conduction ◽  
Recent Observation ◽  
Ionic Conductivities ◽  
Sodium Aluminate ◽  
Two Dimensions ◽  
Ionic Conductors ◽  
Electron Microscopic ◽  
Transmission Electron ◽  
Trivalent Cations

Na ß“-alumina (Na1.67Mg67Al10.33O17) is a non-stoichiometric sodium aluminate which exhibits fast ionic conduction of the Na+ ions in two dimensions. The Na+ ions can be exchanged with a variety of mono-, di-, and trivalent cations. The resulting exchanged materials also show high ionic conductivities.Considerable interest in the Na+-Nd3+-ß“-aluminas has been generated as a result of the recent observation of lasing in the pulsed and cw modes. A recent TEM investigation on a 100% exchanged Nd ß“-alumina sample found evidence for the intergrowth of two different structure types. Microdiffraction revealed an ordered phase coexisting with an apparently disordered phase, in which the cations are completely randomized in two dimensions. If an order-disorder transition is present then the cooling rates would be expected to affect the microstructures of these materials which may in turn affect the optical properties. The purpose of this work was to investigate the affect of thermal treatments upon the micro-structural and optical properties of these materials.

Synthesis of carbonate esters by carboxymethylation using NaAlO2 as a highly active heterogeneous catalyst

2018 ◽  
Author(s):  
Sreerangappa Ramesh ◽  
Kiran Indukuri ◽  
Olivier Riant ◽  
Damien Debecker
Keyword(s):  
Heterogeneous Catalyst ◽  
Dimethyl Carbonate ◽  
Sodium Aluminate ◽  
High Yield ◽  
Solid Catalyst ◽  
Highly Active ◽  
Aromatic Alcohols ◽  
Green Conditions ◽  
Mixed Carbonate

<p>Sodium aluminate is presented as a highly active heterogeneous catalyst able to convert a range of alcohols into the corresponding mixed carbonate esters, in high yield and under green conditions. The reaction is carried out using dimethyl carbonate both as a reactant and solvent, at 90°C. Allylic, aliphatic and aromatic alcohols are converted in good yields. The solid catalyst is shown to be truly heterogeneous, resistant to leaching, and recyclable. </p>

Concrete mechanical behaviour and calcium leaching weak coupling

2006 ◽  
Vol 10 (9) ◽  
pp. 1147-1175 ◽  
Author(s):  
Laurie Lacarrièrre ◽  
Alain Sellier ◽  
Xavier Bourbon
Keyword(s):  
Mechanical Behaviour ◽  
Weak Coupling ◽  
Calcium Leaching

Impact of calcium leaching on mechanical and physical behaviors of high belite cement pastes

2021 ◽  
Vol 286 ◽  
pp. 122983
Author(s):  
Chunmeng Jiang ◽  
Linhua Jiang ◽  
Xinjun Tang ◽  
Jingwei Gong ◽  
Hongqiang Chu
Keyword(s):  
Cement Pastes ◽  
Calcium Leaching ◽  
Belite Cement
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