A Methodology to Evaluate Long Term Durability of Dam Concrete Due to Calcium Leaching through Microscopic Tests and Numerical Analysis

Hydropower dams are subjected to soft water penetration during their service lives. Concrete deterioration due to calcium leaching will decrease the durability of concrete and affect dam safety. The long-term performance of concrete dams due to calcium leaching should be evaluated and predicted accurately to complete reinforcement work in a timely manner. In this paper, a methodology that combined microscopic tests and numerical analysis to evaluate the long-term performance of dam concrete due to calcium leaching is proposed. The current state of concrete is evaluated by analyzing the components of sediments and seepage water through microscopic and spectroscopic tests, such as X-ray photoelectron spectroscopy, scanning electron microscopy, and inductively coupled plasma mass spectrometry. The long-term degradation of concrete was predicted by utilizing a multi-scale model of calcium leaching, which considered the micro-pore structure of cement hydrates flux with time. The simulated results using this calcium leaching model showed a good agreement with other experiments. Finally, a real case study including field inspection was performed and the long-term durability of dam concrete was predicted through microscopic tests and finite element analysis method. It implies that the proposed method could provide calculation and theoretical basis for the durability analysis of concrete dams due to calcium leaching.

Numerical Analysis of Concrete Gravity Dam Seepage Characteristics Evolution considering the Calcium Leaching Effect

During the long-term service life of hydraulic structures, the calcium compounds in cement-based materials decompose in the aqueous environment, leading to the continuous change of seepage characteristics. To study the influence of calcium leaching on the concrete dam seepage characteristics, we proposed a new mathematic model of the cement-based material calcium leaching model under advection-diffusion-driven leaching. A solid-liquid nonequilibrium model is adopted to model the decomposition of calcium hydroxide (CH) and calcium silicate hydrate gel (C-S-H). To calculate the porosity more accurately, the proposed model takes the effect of different calcium compound decomposition on the porosity increase in consideration, respectively. Shimantan dam is selected for the three-dimensional (3D) calcium leaching analyses. The 3D finite element model of this dam is analyzed using COMSOL Multiphysics software that is based on the finite element method. Based on the proposed model, seepage characteristics evolutions of the Shimantan dam are studied. Good agreement between the numerical results and the monitored data indicates the accuracy of this simulation. The result shows that after 100 a leaching duration, the uplift pressure increases by 40.8%, and the leakage quantities of the dam body and foundation increase by 48 and 17 times. The rise of uplift pressure and leakage changes caused by curtain deterioration are the main influences of calcium leaching on the dam seepage. The parameter sensitivity results show that it is necessary to reduce CH content in cement-based materials to obtain better calcium leaching durability. This model and simulation results can guide the operation of concrete dams under advection-diffusion-driven leaching.

Effect of Fly Ash on Leaching Characteristics of Cement-Stabilized Macadam Base

To study the leaching characteristics of a cement-stabilized macadam base with fly ash, a calcium leaching test, using varying cement and fly ash dosages in an ammonium chloride solution, was designed to obtain the rate of calcium ion leaching, porosity, and permeability coefficient of cement-stabilized macadam with leaching time. The results showed that the number of leached calcium ions increased with the cement dosage in the leaching of cement-stabilized macadam. With an increase in the cement dosage, the leaching rate of calcium ions decreased, and the leaching process of the material was delayed. The incorporation of fly ash could effectively slow down the degree of calcium ion leaching. The permeability coefficient increased gradually with the extension of leaching time, and the increase in fly ash content had a more significant effect on the improvement of the permeability coefficient than the increase in cement dosage did.