Behaviour of biomolecules in water-organic solvent-inorganic salt two-phase ternary systems

1981 ◽  
Vol 216 ◽  
pp. 346-349 ◽  
Author(s):  
Vladimir Yur'evich Ryashentsev ◽  
Mikhail Arkad'evich Voskoboinikov ◽  
Efim Semenovich Vainerman ◽  
Sergei Vasil'evich Rogozhin
1984 ◽  
Vol 288 ◽  
pp. 43-49 ◽  
Author(s):  
V.Yu. Ryashentsev ◽  
E.S. Vainerman ◽  
S.V. Rogozhin

The liquid-vapour equilibrium of the system methane-ethylene has been determined at 0, -42 , -78, -88 and -104° C over a wide range of pressures and the results are shown on a pressure-composition-temperature diagram and by a series of pressure-composition curves. The liquid-vapour equilibrium of the ternary system methane-ethane-ethylene has been determined at -104, -78 and 0° C. Values for the two binary systems methane-ethane and methane-ethylene and for the ternary system methane-ethane-ethylene are shown on a composite pressure-composition diagram.


Author(s):  
A. V. Frolkova ◽  
M. A. Ablizin ◽  
M. A. Mayevskiy ◽  
A. K. Frolkova

An approach to the determination of free variables required for calculating the material balance of the flowsheet of ternary mixtures separation is presented. Phase diagrams of the considered ternary systems are characterized by the presence of a two-phase splitting area and by the presence of different amounts of azeotropes (classes 3.1.0, 3.1.1, 3.2.1 and 3.3.1). For all the systems flowsheets containing three rectification columns and a florentine vessel for separation were suggested. The multivariance of the solution of the balance problem was shown. The approach was illustrated by the example of real ternary systems characterized by different phase diagrams (methanol - chloroform - water, butyl alcohol - water - toluene, nitromethane - hexane - water). The parameters of the rectification columns were presented.


Existing physical and thermal data relative to propane have been summarized and correlated, and some new experimental determinations of pressure-volume-temperature relationships for the liquid at low temperatures have been carried out to make good deficiencies in the literature. On the basis of the information thus obtained the entropy and enthalpy of propane have been calculated for conditions of temperature between — 80 and 200° C, and at pressures of from 0.1 to 200 atm. The results are tabulated and also presented graphically on a temperature base.


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