Observations on the gas—liquid chromatography of m-monoalkenes with reference to the systematic identification of esters of unsaturated fatty acids through separation factors and log retention time plots

1963 ◽  
Vol 12 ◽  
pp. 271-276 ◽  
Author(s):  
R.G. Ackman
1967 ◽  
Vol 45 (13) ◽  
pp. 1405-1410 ◽  
Author(s):  
John D. Castell ◽  
R. G. Ackman

The total acidic products from the performic acid oxidation of the ozonide of methyl oleate formed in methanol may be esterified directly in a few hours with 2,2-dimethoxypropane. The ester concentrations are adequate for the determination of the positional isomers of monoethylenic fatty acids directly from the reaction mixture, using a hydrogen flame ionization gas–liquid chromatography detector. Dimethyl sulfoxide was not required to prevent the breakdown of 2,2-dimethoxypropane under the conditions employed.


1963 ◽  
Vol 20 (1) ◽  
pp. 89-94 ◽  
Author(s):  
P. M. Jangaard ◽  
R. G. Ackman ◽  
R. D. Burgher ◽  
M. L. Hughes

The effect of air blowing at two temperatures, 80 and 130 °C, on the major component fatty acids of cod liver oil has been determined. As expected, the proportions of the highly unsaturated fatty acids drop rapidly, especially at the higher temperature investigated. The saturated acids are virtually unchanged under the conditions employed, while the proportion of monounsaturated acids shows only a slight drop.


1970 ◽  
Vol 24 (2) ◽  
pp. 202-208 ◽  
Author(s):  
Mohammad Mizanur Rahman ◽  
Mohammad Shahjahan

Fatty acid composition of Nyctanthes arbortristis Linn root extracted successively  with light petroleum ether (40-600C bp.)- n-hexane and chloroform were analyzed by gas liquid chromatography (GLC). Twenty one fatty acids were identified in the Seuli root. The major saturated and unsaturated fatty acids are palmitic acid (C16:0, 13.97%) and oleic acid (C18:1, 28.43%). Physio-chemical characteristics, such as iodine value, moisture, ash, lignin and crude fibre of the Seuli root were also determined.   Keywords: Nyctanthes arbortristis Linn; Seuli; root; fatty acid composition; gas liquid chromatography. DOI: http://dx.doi.org/10.3329/jbcs.v24i2.9709 Journal of Bangladesh Chemical Society, Vol. 24(2), 202-208, 2011


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