Fiber optic-based interface for on-line selective photometric determinations in solid samples by supercritical fluid extraction

1996 ◽  
Vol 753 (2) ◽  
pp. 299-305 ◽  
Author(s):  
M.T. Tena ◽  
M. Valcárcel
Keyword(s):  
Supercritical Fluid Extraction ◽  
Supercritical Fluid ◽  
Fiber Optic ◽  
Fluid Extraction ◽  
Solid Samples ◽  
On Line

Analysis of Polychlonnated Biphenyls in Fatty Biological Matrixes by On-Line Supercritical Fluid Extraction and Supercritical Fluid Cleanup

1995 ◽  
Vol 78 (4) ◽  
pp. 1051-1054 ◽  
Author(s):  
Earl G Alley ◽  
Guozhen Lu
Keyword(s):  
Supercritical Fluid Extraction ◽  
Supercritical Fluid ◽  
Silica Gel ◽  
Supercritical Co2 ◽  
Functionalized Silica ◽  
Fluid Extraction ◽  
Extraction And Separation ◽  
On Line ◽  
Chromatographic Media ◽  
Level Analysis

Abstract We present a method that combines the extraction of polychlonnated biphenyls (PCBs) and their separation from relatively large quantities of fat in biological matrixes by combined supercritical fluid extraction and separation. Cyano-functionalized silica gel, silica gel, aluminum oxide, Florisil, 3-aminopropyl- functionalized silica gel, and octadecyl-functionalized silica gel were tested for suitability as chromatographic media for separation of PCBs from lipids. Silica gel, 3-aminopropyl-functionalized silica gel, and Florisil adequately separated PCBs from lipids when eluted with supercritical CO2. Florisil allowed both the extraction of PCBs and their separation from lipids in PCB-spiked chicken egg and fish. Two grams of sample containing PCBs at 0.125 μg/g was sufficient for subsequent separations and the low-level analysis required for the more toxic PCB components.

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