A theory of magnetism for semi-metallic uranium compounds

1973 ◽  
Vol 34 (9) ◽  
pp. 1537-1542 ◽  
Author(s):  
H. Adachi ◽  
S. Imoto
1999 ◽  
Vol 60 (15) ◽  
pp. 10606-10609 ◽  
Author(s):  
P. Dalmas de Réotier ◽  
A. Yaouanc ◽  
G. van der Laan ◽  
N. Kernavanois ◽  
J.-P. Sanchez ◽  
...  

1993 ◽  
Vol 48 (1) ◽  
pp. 52-57 ◽  
Author(s):  
Wolfgang Jeitschko ◽  
Reinhold Brink ◽  
Peter G. Pollmeier

The title compounds were prepared from prereacted samples of the elemental components by arc-melting. UCr5P3 was also obtained from a tin flux. UV5P3 and UCr5P3 crystallize with a new structure type, which was determined from X -ray data of a twinned crystal of UCr5P3 :P21/m, a = 959.1(2), b = 370.95(6), c = 696.7(1) pm , β = 100.05(3)°, Z = 2, R = 0.030 for 827 structure factors and 29 variable parameters. UMn5P3 is isotypic with YCo5P3. The structure was refined to a residual of R = 0.054 for 455 structure factors and 28 variables. UCr5P3 has a relatively high, almost temperature independent paramagnetic susceptibility as is frequently observed for metallic uranium compounds. The crystal structures of these phosphides are discussed together with those of other phosphides and silicides of similar composition.


Author(s):  
David L. Monts ◽  
Guangjun Wang ◽  
Yi Su ◽  
Ping-Rey Jang ◽  
Charles A. Waggoner

In the environment, metallic uranium readily oxidizes to form uranium compounds that contain the uranyl (UO2+2) moiety. For more than a hundred and fifty years, it has been known that when illuminated with ultraviolet (UV) light, uranyl compounds exhibit characteristic fluorescence in the visible region (450–650 nm). We report our efforts to develop a transportable, quantitative Fluorescence Spectral Imaging (FSI) system as a tool for locating and quantifying uranyl compounds dispersed in soils and on other surfaces. A project is underway to develop a set of sensors to locate expended depleted uranium (DU) rounds and to process soil and debris to recover the material from domestic firing ranges. The FSI system can also be utilized to monitor excavation of DU munitions and separation of uranyl compounds from soils. FSI images are acquired by illuminating a surface with a UV light and using a narrow bandpass filter on a camera, recording an image of the resulting fluorescence. The FSI image provides both spatial and spectral information. The FSI system is described and its performance characterized using field samples.


1979 ◽  
Vol 40 (C4) ◽  
pp. C4-22-C4-23 ◽  
Author(s):  
J. Keller ◽  
M. Erbudak

1979 ◽  
Vol 40 (C4) ◽  
pp. C4-19-C4-21 ◽  
Author(s):  
R. Allen ◽  
M. S.S. Brooks

1986 ◽  
Vol 64 (1-2) ◽  
pp. 87-104 ◽  
Author(s):  
N. E. Alekseevskii ◽  
V. I. Nizhankovskii ◽  
V. N. Narozhnyi ◽  
E. P. Khlybov ◽  
A. V. Mitin
Keyword(s):  

2021 ◽  
Author(s):  
Nikolay G. Chernorukov ◽  
Oxana V. Nipruk ◽  
Kseniya A. Klinshova ◽  
Olga N. Tumaeva ◽  
Dmitry V. Sokolov

A series of new uranium compounds [MII(H2O)3][(UO2)3O3(OH)2]·2H2O (MII – Mn, Co, Ni, Zn) were synthesized for binding radionuclides in the environment and nuclear fuel cycle.


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