Heat capacity by sawtooth-modulated, standard heat-flux differential scanning calorimeter with close control of the heater temperature

2001 ◽  
Vol 367-368 ◽  
pp. 229-238 ◽  
Author(s):  
Jeongihm Pak ◽  
Bernhard Wunderlich
1995 ◽  
Vol 269-270 ◽  
pp. 51-60 ◽  
Author(s):  
Teresa M.V.R. de Barros ◽  
Rui C. Santos ◽  
Anabela C. Fernandes ◽  
Manuel E.Minas da Piedade

Author(s):  
V.N. Moraru

The results of our work and a number of foreign studies indicate that the sharp increase in the heat transfer parameters (specific heat flux q and heat transfer coefficient _) at the boiling of nanofluids as compared to the base liquid (water) is due not only and not so much to the increase of the thermal conductivity of the nanofluids, but an intensification of the boiling process caused by a change in the state of the heating surface, its topological and chemical properties (porosity, roughness, wettability). The latter leads to a change in the internal characteristics of the boiling process and the average temperature of the superheated liquid layer. This circumstance makes it possible, on the basis of physical models of the liquids boiling and taking into account the parameters of the surface state (temperature, pressure) and properties of the coolant (the density and heat capacity of the liquid, the specific heat of vaporization and the heat capacity of the vapor), and also the internal characteristics of the boiling of liquids, to calculate the value of specific heat flux q. In this paper, the difference in the mechanisms of heat transfer during the boiling of single-phase (water) and two-phase nanofluids has been studied and a quantitative estimate of the q values for the boiling of the nanofluid is carried out based on the internal characteristics of the boiling process. The satisfactory agreement of the calculated values with the experimental data is a confirmation that the key factor in the growth of the heat transfer intensity at the boiling of nanofluids is indeed a change in the nature and microrelief of the heating surface. Bibl. 20, Fig. 9, Tab. 2.


1991 ◽  
Vol 69 (3) ◽  
pp. 440-450
Author(s):  
Utpal Sen

A theory composite of the scaled particle theory and the Born model of solvent continuum has been used to theoretically calculate the standard heat capacity of hydration as well as the partial molal heat capacity of aqueous ions and electrolytes at elevated temperatures. The uncertainties in the second temperature derivatives of solvent dielectric constant at various temperatures present a barrier to an accurate heat capacity prediction by the theory. Nevertheless, the agreement between the predicted standard heat capacity of electrolytes in solution and the corresponding experimental data, particularly at higher temperatures, is encouraging. Moreover, the composite theory seems to provide the most accurate thermodynamic predictions to date for aqueous electrolytes at higher temperatures without involving any arbitrary adjustable parameter. We therefore use this theory to find the proper ionic scale of the partial molal heat capacities at elevated temperatures. Key words: scaled particle theory, solvent continuum model of Born, standard heat capacity of aqueous ions, absolute scale for hydration thermodynamic quantities.


Author(s):  
Nataliia Fialko ◽  
◽  
Viktor Prokopov ◽  
Nataliia Meranova ◽  
Sergey Aleshko ◽  
...  

The data of CFD analysis of the specific heat capacity fields of supercritical water in round channels at different values of the heat flux supplied to the wall are presented.


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