99/00674 The kinetics of gasification and combustion of various wastes, biomasses, and coals in the bubbling fluidized bed

1999 ◽  
Vol 40 (1) ◽  
pp. 67
Author(s):  
A. T. Harris ◽  
S. A. Scott ◽  
J. S. Dennis ◽  
A. N. Hayhurst ◽  
J. F. Davidson

This paper gives the first measurements from a project investigating the gasification of dried sewage sludge in a laboratory scale, bubbling fluidized bed at atmospheric pressure. The aim of the work was to examine the reactions occurring in a fluidized bed gasifier rather than simply treat the reactor as a ‘black box’. Experiments were performed to investigate the rates of drying, devolatilisation, gasification and combustion. Thermogravimetric analysis, as well as batch fluidized bed experiments using mechanically dewatered, dried and pelletised municipal sewage sludges from different regions in the UK were performed. A comparison was made between the different samples of sludge and a low rank coal and softwood biomass. A distributed activation energy model (DAEM) for interpreting the kinetics of devolatilisation was also investigated. The model was able to reduce the results from several TGA experiments to a single curve characterised by a single parameter, the pre-exponential factor, A.


2022 ◽  
Vol 237 ◽  
pp. 111871
Author(s):  
Zhenting Zha ◽  
Zefeng Ge ◽  
Yuna Ma ◽  
Mingxun Zeng ◽  
Yujie Tao ◽  
...  

1993 ◽  
Vol 28 (2) ◽  
pp. 135-144 ◽  
Author(s):  
S. Matsui ◽  
R. Ikemoto Yamamoto ◽  
Y. Tsuchiya ◽  
B. Inanc

Using a fluidized bed reactor, experiments on glucose decomposition with and without sulfate reduction were conducted. Glucose in the reactor was mainly decomposed into lactate and ethanol. Lactate was mainly decomposed into propionate and acetate, while ethanol was decomposed into propionate, acetate, and hydrogen. Sulfate reduction was not involved in the decomposition of glucose, lactate, and ethanol, but was related to propionate and acetate decomposition. The stepwise reactions were modeled using either a Monod expression or first order reaction kinetics in respect to the reactions. The coefficients of the kinetic equations were determined experimentally. The modified Monod and first order reaction equations were effective at predicting concentrations of glucose, lactate, ethanol, propionate, acetate, and sulfate along the beight of the reactor. With sulfate reduction, propionate was decomposed into acetate, while without sulfate reduction, accumulation of propionate was observed in the reactor. Sulfate reduction accelerated propionate conversion into acetate by decreasing the hydrogen concentration.


2021 ◽  
Vol 229 ◽  
pp. 113749
Author(s):  
D.T. Pio ◽  
L.C.M. Ruivo ◽  
L.A.C. Tarelho ◽  
J.R. Frade ◽  
E. Kantarelis ◽  
...  

2021 ◽  
Vol 235 ◽  
pp. 113981
Author(s):  
M. Puig-Gamero ◽  
D.T. Pio ◽  
L.A.C. Tarelho ◽  
P. Sánchez ◽  
L. Sanchez-Silva

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