New flowsheet for the recovery of cadmium, cobalt and nickel from spent Ni–Cd batteries by solvent extraction

1999 ◽  
Vol 52 (3) ◽  
pp. 267-287 ◽  
Author(s):  
C.A Nogueira ◽  
F Delmas
2006 ◽  
Vol 51 (3) ◽  
pp. 265-271 ◽  
Author(s):  
Kyung Ho Park ◽  
B. Ramachandra Reddy ◽  
Sun Hee Jung ◽  
D. Mohapatra

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 662
Author(s):  
Wen-Yu Wang ◽  
Hong-Chi Yang ◽  
Ren-Bin Xu

The annual global volume of waste lithium-ion batteries (LIBs) has been increasing over years. Although solvent extraction method seems well developed, the separation factor between cobalt and nickel is still relatively low—only 72 when applying conventional continuous-countercurrent extraction. In this study, we improved the separation factor of cobalt and nickel by complexation-assisted solvent extraction. Before solvent extraction procedure, leaching kinetic of Li, Ni, Co and Mn was studied and can be explained by the Avrami equation. Leached residues were also investigated by SEM and XRD. Operation parameters of complexation-assisted solvent extraction were examined, including volume ratio of extractant to diluent, types of diluent, type of complexing reagent, extractant saponification percentage and volume ratio of organic phase to aqueous phase. The optimal separation factor of complexation-assisted solvent extraction could be improved to 372, which is five times that of conventional solvent extraction. The separation tendency would be interpreted by the relationship between extraction equilibrium pH and log distribution coefficient.


1984 ◽  
Vol 83 (5-6) ◽  
pp. 343-357 ◽  
Author(s):  
A. Izquierdo ◽  
R. Compa�� ◽  
E. Bars

1991 ◽  
Vol 45 ◽  
pp. 383-391 ◽  
Author(s):  
Ting-Chia Huang ◽  
Teh-Hua Tsai ◽  
Manfred Mühlstädt ◽  
Kari Rissanen ◽  
Katri Laihia ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document