Characterization of azurite and lazurite based pigments by laser induced breakdown spectroscopy and micro-Raman spectroscopy

2001 ◽  
Vol 56 (6) ◽  
pp. 915-922 ◽  
Author(s):  
M Bicchieri ◽  
M Nardone ◽  
P.A Russo ◽  
A Sodo ◽  
M Corsi ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Micro Raman Spectroscopy ◽  
Laser Induced Breakdown

EXPRESS: Combined Spectroscopic Analysis of Terrestrial Analogs from a Simulated Astronaut Mission Using the Laser-Induced Breakdown Spectroscopy (LIBS) Raman Sensor: Implications for Mars

2021 ◽  
pp. 000370282110168
Author(s):  
Emmanuel Lalla ◽  
Menelaos Konstantinidis ◽  
Elizabeth A. Lymer ◽  
Cosette G. Gilmour ◽  
James Freemantle ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Test Site ◽  
Planetary Exploration ◽  
Laser Induced Breakdown Spectroscopy ◽  
Biological Processes ◽  
Time Resolved ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Raman Sensor

One of the primary objectives of planetary exploration is the search for signs of life (past, present, or future). Formulating an understanding of the geochemical processes on planetary bodies may allow us to define the precursors for biological processes, thus providing insight into the evolution of past life on Earth and other planets, and perhaps a projection into future biological processes. Several techniques have emerged for detecting biomarker signals on an atomic or molecular level, including laser-induced breakdown spectroscopy (LIBS), Raman spectroscopy, laser-induced fluorescence spectroscopy (LIF), and attenuated total reflectance Fourier-transform infrared (ATR-FTIR) spectroscopy, each of which addresses complementary aspects of the elemental composition, mineralogy, and organic characterization of a sample. However, given the technical challenges inherent to planetary exploration, having a sound understanding of the data provided from these technologies, and how the inferred insights may be used synergistically is critical for mission success. In this work, we present an in-depth characterization of a set of samples collected during a 28-day Mars analogue mission conducted by the Austrian Space Forum in the Dhofar region of Oman. The samples were obtained under high-fidelity spaceflight conditions and by taking into account the geological context of the test site. The specimens were analyzed using the LIBS/Raman Sensor (LIRS)⁠—a prototype instrument for future exploration of Mars. We present the elemental quantification of the samples obtained from LIBS using a previously developed linear mixture model, and validated by Scanning Electron Microscopy/Energy Dispersive Spectroscopy (SEM/EDS). Moreover, we provide a full mineral characterization obtained using UV Raman spectroscopy and LIF, which was verified through ATR-FTIR. Lastly, we present possible discrimination of organics in the samples using LIF and time-resolved LIF. Each of these methods yields accurate results, with low errors in their predictive capabilities of LIBS (median relative error ranging from 4.5% to 16.2%), and degree of richness in subsequent inferences to geochemical and potential biochemical processes of the samples. The existence of such methods of inference and our ability to understand the limitations thereof is crucial for future planetary missions, not only to Mars and Moon but also for future exoplanetary exploration.

Characterization of Amethysts from Sukamara, Central Kalimantan, Using Laser-Induced Breakdown Spectroscopy (LIBS)

2020 ◽  
Vol 1 (2) ◽  
pp. 5-8
Author(s):  
Komang Gde Suastika, Heri Suyanto, Gunarjo, Sadiana, Darmaji
Keyword(s):  
Emission Intensity ◽  
Laser Energy ◽  
Emission Spectra ◽  
Atomic Emission ◽  
Laser Induced Breakdown Spectroscopy ◽  
Chemical Formula ◽  
Central Kalimantan ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

Abstract - Laser-Induced Breakdown Spectroscopy (LIBS) is one method of atomic emission spectroscopy using laser ablation as an energy source. This method is used to characterize the type of amethysts that originally come from Sukamara, Central Kalimantan. The result of amethyst characterization can be used as a reference for claiming the natural wealth of the amethyst. The amethyst samples are directly taken from the amethyst mining field in the District Gem Amethyst and consist of four color variations: white, black, yellow, and purple. These samples were analyzed by LIBS, using laser energy of 120 mJ, delay time detection of 2 μs and accumulation of 3, with and without cleaning. The purpose of this study is to determine emission spectra characteristics, contained elements, and physical characteristics of each amethyst sample. The spectra show that the amethyst samples contain some elements such as Al, Ca, K, Fe, Gd, Ba, Si, Be, H, O, N, Cl and Pu with various emission intensities. The value of emission intensity corresponds to concentration of element in the sample. Hence, the characteristics of the amethysts are based on their concentration value. The element with the highest concentration in all samples is Si, which is related to the chemical formula of SiO2. The element with the lowest concentration in all samples is Ca that is found in black and yellow amethysts. The emission intensity of Fe element can distinguish between white, purple, and yellow amethyst. If Fe emission intensity is very low, it indicates yellow sample. Thus, we may conclude that LIBS is a method that can be used to characterize the amethyst samples.Key words: amethyst, impurity, laser-induced, breakdown spectroscopy, characteristic, gemstones

Characterization of Hygroscopic Insulator Contamination via Laser-Induced Breakdown Spectroscopy

2021 ◽  
Vol 49 (3) ◽  
pp. 1166-1172
Author(s):  
Xinran Qin ◽  
Fuzeng Zhang ◽  
Shaojie Chen ◽  
Tingting Wang ◽  
Xiao Hong ◽  
...  
Keyword(s):  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

Characterization of ion irradiated silicon surfaces ablated by laser-induced breakdown spectroscopy

2018 ◽  
Vol 27 (8) ◽  
pp. 087401 ◽  
Author(s):  
T Iqbal ◽  
M Abrar ◽  
M B Tahir ◽  
M Seemab ◽  
A Majid ◽  
...  
Keyword(s):  
Silicon Surfaces ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

LIBS for the Analysis of Metallurgical and Solar Grade Silicon

2011 ◽  
Vol 324 ◽  
pp. 324-327 ◽  
Author(s):  
Sarah Darwiche ◽  
Malek Benmansour ◽  
Nir Eliezer ◽  
Daniel Morvan
Keyword(s):  
Chemical Characterization ◽  
Laser Induced Breakdown Spectroscopy ◽  
Solar Grade Silicon ◽  
Photovoltaic Panels ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Elemental Chemical Analysis ◽  
Boron Analysis ◽  
Grade Silicon

Laser-induced breakdown spectroscopy (LIBS) has been employed for the fast and reliable chemical characterization of silicon used for the photovoltaic industry. Silicon for photovoltaic panels is subject to certain constraints on its purity, and notably must contain low concentration of boron. The use of LIBS could be advantageous because it allows rapid and simultaneous multi-elemental chemical analysis of silicon without any sample preparation. LIBS was applied to boron analysis and a detection limit of 0.23 ppmw was found for optimized gas and pressure conditions.

Highly depth-resolved characterization of fusion-related tungsten material based on picosecond laser-induced breakdown spectroscopy

2020 ◽  
Vol 35 (12) ◽  
pp. 2867-2879
Author(s):  
Dongye Zhao ◽  
Ding Wu ◽  
Jannis Oelmann ◽  
Sebastijan Brezinsek ◽  
Qingmei Xiao ◽  
...  
Keyword(s):  
Nuclear Fusion ◽  
Picosecond Laser ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Potential Applications ◽  
Tungsten Material

The objective of the present study has been to evaluate the potential applications of picosecond laser-induced breakdown spectroscopy (ps-LIBS) in nuclear fusion devices.

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