Ammonia activation over catalysts for the selective catalytic reduction of NOx and the selective catalytic oxidation of NH3. An FT-IR study

1996 ◽  
Vol 28 (4) ◽  
pp. 373-380 ◽  
Author(s):  
G. Ramis ◽  
Li Yi ◽  
G. Busca
2006 ◽  
Vol 113 (1-2) ◽  
pp. 87-93 ◽  
Author(s):  
F. Romero Sarria ◽  
O. Marie ◽  
P. Bazin ◽  
J. Saussey ◽  
J. Lesage ◽  
...  

Catalysts ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 399 ◽  
Author(s):  
Donghai An ◽  
Xiaoyang Zhang ◽  
Xingxing Cheng ◽  
Yong Dong

A series of composites of Mn-Fe-Ce/GO-x have been synthesized by a hydrothermal method. Their performance in simultaneously performing the catalytic oxidation of Hg0 and the selective catalytic reduction of nitrogen oxides (NOx) in the same temperature range were investigated. In order to investigate the physicochemical properties and surface reaction, basic tests, including Brunauer-Emmett-Teller (BET), XRD, scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS) were selected. The results indicate that the active components deposited on graphene play an important role in the removal of mercury and NOx, with different valences. Especially, the catalyst of Mn-Fe-Ce/GO-20% possesses an excellent efficiency in the temperature range of 170 to 250 °C. Graphene has a huge specific surface area and good mechanical property; thus, the active components of the Mn-Fe-Ce catalyst can be highly dispersed on the surface of graphene oxide. In addition, the effects of O2, H2O, NO and SO2 on the removal efficiency of Hg0 were examined in flue gas. Furthermore, the regeneration experiments conducted by thermal methods proved to be promising methods.


2018 ◽  
Vol 8 (4) ◽  
pp. 1028-1038 ◽  
Author(s):  
Ramon Oord ◽  
Joel E. Schmidt ◽  
Bert M. Weckhuysen

Using in situ FT-IR and operando UV-vis-NIR DRS, performed on a series of different Cu–ion-exchanged SSZ-13 zeolites, both a mono-nuclear site or a dimeric copper active site are consistent for methane-to-methanol activation.


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