scholarly journals Die sinter bonding in air using copper formate preform for formation of full-density bondline

2021 ◽  
Vol 31 (6) ◽  
pp. 1717-1728
Author(s):  
Yun-Ju LEE ◽  
Jong-Hyun LEE
2013 ◽  
Vol 1 (1) ◽  
Author(s):  
Thomas Martens ◽  
M. Laine Mears

In the metal injection molding (MIM) process, fine metal powders are mixed with a binder and injected into molds, similar to plastic injection molding. After molding, the binder is removed from the part, and the compact is sintered to almost full density. Though able to create high-density parts of excellent dimensional control and surface finish, the MIM process is restricted in the size of part that can be produced, due to gravitational deformation during high-temperature sintering and maximum thickness requirements to remove the binding agents in the green state. Larger parts could be made by bonding the green parts to a substrate during sintering; however, a primary obstacle to this approach lies in the sinter shrinkage of the MIM part, which can be up to 20%, meaning that the MIM part shrinks during sintering, while the conventional substrate maintains its dimensions. This behavior would typically inhibit bonding and/or cause cracking and deformation of the MIM part. In this work, we present a structure of micro features molded onto the surface of the MIM part, which bonds, deforms, and allows for shrinkage while bonding to the substrate. The micro features tolerate plastic deformation to permit the shrinkage without causing cracks after the initial bonds are established. In a first series of tests, bond strengths of up to 80% of that of resistance welds have been achieved. This paper describes how the authors developed their proposed method of sinter bonding and how they accomplished effective sinter bonds between MIM parts and solid substrates.


Author(s):  
Thomas Martens ◽  
Laine Mears

In MIM, fine metal powders are mixed with a binder and injected into molds, similar to plastic injection molding. After molding, the binder is removed from the part, and the compact is sintered to almost full density. The obstacle to sinter bonding a MIM part to a conventional (solid) substrate lies in the sinter shrinkage of the MIM part, which can be up to 20%, meaning that the MIM part shrinks during sintering, while the conventional substrate maintains its dimensions. This behavior would typically inhibit bonding and/or cause cracking and deformation of the MIM part. A structure of micro features molded onto the surface of the MIM part allows for shrinkage while bonding to the substrate. The micro features tolerate certain plastic deformation to permit the shrinkage without causing cracks after the initial bonds are established. In a first series of tests, bond strengths of up to 80% of that of resistance welds have been achieved. This paper describes how the authors developed their proposed method of sinter bonding and how they accomplished effective sinter bonds between MIM parts and solid substrates.


2020 ◽  
Vol 63 (5) ◽  
pp. 367-380
Author(s):  
Sung Yoon Kim ◽  
Eun Byeol Choi ◽  
Dong-Hyun Joo ◽  
Jong-Hyun Lee

Author(s):  
J. W. Mellowes ◽  
C. M. Chun ◽  
I. A. Aksay

Mullite (3Al2O32SiO2) can be fabricated by transient viscous sintering using composite particles which consist of inner cores of a-alumina and outer coatings of amorphous silica. Powder compacts prepared with these particles are sintered to almost full density at relatively low temperatures (~1300°C) and converted to dense, fine-grained mullite at higher temperatures (>1500°C) by reaction between the alumina core and the silica coating. In order to achieve complete mullitization, optimal conditions for coating alumina particles with amorphous silica must be achieved. Formation of amorphous silica can occur in solution (homogeneous nucleation) or on the surface of alumina (heterogeneous nucleation) depending on the degree of supersaturation of the solvent in which the particles are immersed. Successful coating of silica on alumina occurs when heterogeneous nucleation is promoted and homogeneous nucleation is suppressed. Therefore, one key to successful coating is an understanding of the factors such as pH and concentration that control silica nucleation in aqueous solutions. In the current work, we use TEM to determine the optimal conditions of this processing.


Author(s):  
Gyeung Ho Kim ◽  
Mehmet Sarikaya ◽  
D. L. Milius ◽  
I. A. Aksay

Cermets are designed to optimize the mechanical properties of ceramics (hard and strong component) and metals (ductile and tough component) into one system. However, the processing of such systems is a problem in obtaining fully dense composite without deleterious reaction products. In the lightweight (2.65 g/cc) B4C-Al cermet, many of the processing problems have been circumvented. It is now possible to process fully dense B4C-Al cermet with tailored microstructures and achieve unique combination of mechanical properties (fracture strength of over 600 MPa and fracture toughness of 12 MPa-m1/2). In this paper, microstructure and fractography of B4C-Al cermets, tested under dynamic and static loading conditions, are described.The cermet is prepared by infiltration of Al at 1150°C into partially sintered B4C compact under vacuum to full density. Fracture surface replicas were prepared by using cellulose acetate and thin-film carbon deposition. Samples were observed with a Philips 3000 at 100 kV.


2018 ◽  
Vol 941 ◽  
pp. 1276-1281
Author(s):  
Anna Terynková ◽  
Jiří Kozlík ◽  
Kristína Bartha ◽  
Tomáš Chráska ◽  
Josef Stráský

Ti-15Mo alloy belongs to metastable β-Ti alloys that are currently used in aircraft manufacturing and Ti15Mo alloy is a perspective candidate for the use in medicine thanks to its biotolerant composition. In this study, Ti15Mo alloy was prepared by advanced techniques of powder metallurgy. The powder of gas atomized Ti-15Mo alloy was subjected to cryogenic milling to achieve ultra-fine grained microstructure within the powder particles. Powder was subsequently compacted using spark plasma sintering (SPS). The effect of cryogenic milling on the microstructure and phase composition of final bulk material after SPS was studied by scanning electron microscopy. Sintering at 750°C was not sufficient for achieving full density in gas atomized powder, while milled material could be successfully sintered at this temperature. Alpha phase particles precipitated during sintering and their size, as well as the size of beta matrix grains, was strongly affected by the sintering temperature.


2013 ◽  
Vol 833 ◽  
pp. 125-129
Author(s):  
Hao Zhang ◽  
Zhong Min Zhao ◽  
Long Zhang ◽  
Shuan Jie Wang

By introducing (CrO3+Al) high-energy thermit into (Ti+B4C) system and designing adiabatic temperature of reactive system as 3000°C,3200°C, 3400°C, 3600°C and 3800°C respectively, a series of solidified TiC-TiB2were prepared by combustion synthesis in ultrahigh gravity field with the acceleration 2000 g. XRD, FESEM and EDS results showed that the solidified TiCTiB2were composed of a number of TiB2primary platelets, irregular TiC secondary grains, and a few of isolated Al2O3inclusions and Cr-based alloy. Because of the enhanced Stokes flow in mixed melt with the increased adiabatic temperature, Al2O3droplets were promoted to float up and separate from TiC-TiB2-Me liquid while constitutional distribution became more and more uniform in TiC-TiB2-Me liquid, resulting in not only the sharply-reduced Al2O3inclusions in the solidified ceramic but also the refined microstructure and the improved homogeneity in the ceramic, and ultrafine-grained microstructure with a average thickness of TiB2platelets smaller than 1μm began to appear in near-full-density ceramic as the adiabatic temperature exceeded 3600°C, so the densification, fracture toughness and flexural strength of the ceramic were enhanced with the increased adiabatic temperature of the reactive system.


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