Self-Consistent Thermodynamic Parameters of Diopside at High Temperatures and High Pressures: Implications for the Adiabatic Geotherm of an Eclogitic Upper Mantle

Using an iterative numerical approach, we have obtained the self-consistent thermal expansion, heat capacity, and Grüneisen parameters of diopside (MgCaSi2O6) over wide pressure and temperature ranges based on experimental data from the literature. Our results agree well with the published experimental and theoretical data. The determined thermodynamic parameters exhibit nonlinear dependences with increasing pressure. Compared with other minerals in the upper mantle, we found that the adiabatic temperature gradient obtained using the thermodynamic data of diopside is larger than that of garnet while lower than that of olivine, when ignoring the Fe incorporation. Combining our results with thermodynamic parameters of garnet obtained in previous studies, we have estimated the adiabatic temperature gradient and geotherm of an eclogitic upper mantle in a depth range of 200–450 km. The results show that the estimated adiabatic temperature gradient of the eclogite model is ~16% and ~3% lower than that of the pyrolite model at a depth of 200 km and 410 km, respectively. However, the high mantle potential temperature of the eclogite model leads to a similar temperature as the pyrolite model in a depth range of 200–410 km.

Effects of Different Content of Phosphorus Slag Composite Concrete: Heat Evolution, Sulphate-Corrosion Resistance and Volume Deformation

Phosphorus slag (PS) and limestone (LS) composite (PLC) were prepared with a mass ratio of 1:1. The effects of the content of PLC and the water/binder ratio on the mechanical properties, durability and dry shrinkage of concrete were studied via compressive strength, electric flux, sulfate dry/wet cycle method, saturated drainage method, isothermal calorimeter, adiabatic temperature rise instrument and shrinkage deformation instrument. The results show that PLC can greatly reduce the adiabatic temperature rise of concrete. The adiabatic temperature rise is 55 °C with 33 wt.% PLC, 10 °C lower than that of the control sample. The addition in the content of PLC does not affect the long-term strength of concrete. When the water/binder ratio decreases by 0.1–0.15, the long-term strength of concrete with PLC increases by about 10%, compared with the control group. At the age of 360 days, the chloride permeability of L-11 (i.e., the content of PLC was 20%, the water/binder ratio was 0.418) and L-22 (i.e., the content of PLC was 33%, the water/binder ratio was 0.39) decrease to the “very low” grade. The strength loss rate of L-11 and L-22 after 150 sulfate dry/wet cycles is about 18.5% and 19%, respectively, which is 60% of the strength loss rate of the control sample. The drying shrinkage of L-11 and L-22 reduces by 4.7% and 9.5%, respectively, indicating that PLC can also reduce the drying shrinkage.

Simple and Low-Cost Footstep Energy-Recover Barocaloric Heating and Cooling Device

In this work, we design, build, and test one of the very first barocaloric devices. The here presented device can recover the energy generated by an individual’s footstep and transform it into barocaloric heating and/or cooling. Accordingly, we present an innovative device that can provide eco-friendly and gas-free heating/cooling. Moreover, we test the device by measuring a new barocaloric organic polymer that exhibits a large adiabatic temperature change of ~2.9 K under the application of 380 bar. These results pave the way towards novel and more advanced barocaloric technologies and provide a simple and low-cost device to explore new barocaloric materials.

Electrocaloric Effect of (K1−xNax)NbO3 Single Crystal

The electrocaloric effect of (K1−xNax)NbO3 single crystal is calculated based on Landau-Devonshire theory. The electrocaloric coefficient and adiabatic temperature change are calculated with the variation of temperature in rhombohedral, orthorhombic and tetragonal phase. A maximum of electrocaloric coefficient is obtained in each ferroelectric phase. Moreover, the tetragonal phase presents the larger electrocaloric coefficient and adiabatic temperature change than that rhombohedral and orthorhombic phase. However, the large electrocaloric effect is also obtained at room temperature with the adiabatic temperature change of 0.5 K, which tallies with the experimental findings.

Martensitic transformation, magnetic entropy, and adiabatic temperature changes in bulk and ribbon Ni48Mn39.5Sn12.5−xInx (x = 2, 4, 6) metamagnetic shape memory alloys

Martensitic transformation, magnetic entropy, and direct adiabatic temperature changes in Ni48Mn39.5Sn12.5−xInx (x = 2, 4, 6) metamagnetic Heusler bulk and grain-constrained ribbon alloys were studied. All alloys showed a typical L21 structure in austenite and the 4O structure in martensite. Their relative volume contributions changed depending on In content. With increasing In concentration, the martensitic transformation temperature increased, whereas the Curie temperature of austenite decreased. The magnetic entropy change under magnetic field of 5 T attained maximum of 20 J/kgK in the bulk and 14.4 J/kgK in the ribbon alloys with the Ni48Mn39.5Sn8.5In4 nominal composition. The corresponding adiabatic temperature change under 1.7 T yielded 1.3 K for the Ni48Mn39.5Sn8.5In4 bulk alloy. Despite grain confinement, melt spinning was found to stabilize martensite phase. Changes observed were discussed with relation to strengthened covalency imposed by In substitution. Graphic abstract

Early Cracking Risk Prediction Model of Concrete under the Action of Multifield Coupling

Through the adiabatic temperature rise experiment, the adiabatic temperature rise of concrete with hydration time was recorded. Based on the maturity degree theory, the relationship between the hydration degree of the concrete and the equivalent age was determined. Then, the hydration degree prediction model of the concrete's early elastic modulus and tensile strength was established. The local temperature and humidity of the concrete were measured by the shrinkage experiment, and based on the capillary water tension theory, a temperature-humidity prediction model for the early shrinkage of the concrete was designed. According to the ratio of the creep deformation and elastic deformation of concrete which were obtained through the restraint ring experiment, a model for predicting the early creep coefficient of concrete was proposed. Based on the coupling effect of “hydration-temperature-humidity,” a prediction model of early cracking risk coefficient of concrete under multifield coupling was proposed. Finally, several groups of slab cracking frame experiments were carried out, and the cracking risk prediction results of concrete were consistent with the actual situation, which indicated the correctness of the early cracking risk prediction model of concrete.