Study on Excess Thermodynamic Parameters and Theoretical Estimation of Ultrasonic Velocity Using Scaled Particle Theory in Binary Liquid Mixtures of 2-Methyl-2-propanol and Nitriles at Different Temperatures

2010 ◽  
Vol 18 (5) ◽  
pp. 804-816 ◽  
Author(s):  
K. Rajagopal ◽  
S. Chenthilnath
Keyword(s):  
Thermodynamic Parameters ◽  
Ultrasonic Velocity ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Scaled Particle Theory ◽  
Theoretical Estimation ◽  
Particle Theory ◽  
Binary Liquid ◽  
Excess Thermodynamic Parameters ◽  
Different Temperatures

scholarly journals Experimental and Theoretical Evaluation of Ultrasonic Velocities of Binary Liquid Mixtures of Anisaldehyde and Toluene at Different Temperatures

2011 ◽  
Vol 8 (3) ◽  
pp. 977-981
Author(s):  
CH. Srinivasu ◽  
K. Narendra ◽  
CH. Kalpana
Keyword(s):  
Ultrasonic Velocity ◽  
Theoretical Models ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Different Temperatures ◽  
Experimental Values ◽  
Good Agreement

Theoretical velocities of binary liquid mixtures of anisaldehyde with toluene at 303.15, 308.15, 313.15 and 318.15 K have been evaluated by using theoretical models of liquid mixtures such as Nomoto, Van Dael-Vangeel, Schaff’s collision factor theory and Junjie’s relations. Density and ultrasonic velocity of these mixtures have also been measured as a function of concentration and temperature and the experimental values are compared with the theoretical values. A good agreement has been found between experimental and Nomoto’s theoretical ultrasonic velocities. The results are explained in terms of intermolecular interactions occurring in these binary liquid mixtures.

scholarly journals Theoritical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures ofN-Methyl-2-pyrrolidone at Different Temperatures with Some Cyclic Compounds

2012 ◽  
Vol 9 (2) ◽  
pp. 553-562 ◽  
Author(s):  
K. Rayapa Reddy ◽  
D. Bala Karuna Kumar ◽  
C. Rambabu ◽  
G. Srinivasa Rao
Keyword(s):  
Ultrasonic Velocity ◽  
Interaction Parameter ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Binary Liquid ◽  
Ideal Mixing ◽  
Different Temperatures ◽  
Molecular Interaction Parameter ◽  
Cyclic Compounds

Ultrasonic velocities and densities of the binary liquid mixtures ofN-methyl-2-Pyrrolidone (NMP) with Cyclohexylamine (CHA), Cyclohexanol (CHOL) and Cyclohexene(CHE) at a temperature range of 303.15 to 318.15 K over the entire composition range were measured. The theoretical values of ultrasonic velocity were evaluated using the Nomoto's relation(UNR), Impedence relation(UIR), Ideal mixing relation(UIMR), Jungie's relation(UJR) and Rao's specific velocity relation(UR).The molecular interaction parameter (α) was computed by using the experimental and theoretical ultrasonic velocity values. The variation of interaction parameter with the composition of the mixture has been discussed in terms of molecular interactions.

scholarly journals Acoustical Studies on Molecular Interactions in Binary Liquid Mixtures at 303 K

2009 ◽  
Vol 6 (4) ◽  
pp. 1150-1152 ◽  
Author(s):  
R. Uvarani ◽  
J. Sivapragasam
Keyword(s):  
Ultrasonic Velocity ◽  
Molecular Interactions ◽  
Molecular Interaction ◽  
Binary Systems ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Technique ◽  
Acoustical Parameters ◽  
Binary Liquid ◽  
Excess Parameters

Molecular interaction studies using ultrasonic technique in the binary liquid mixtures of cyclohexanone witho-cresol andp-cresol have been carried out at 303 K. Using the measured values of ultrasonic velocity, density and viscosity, acoustical parameters and their excess values are evaluated. From the properties of these excess parameters the nature and strength of the interactions in these binary systems are discussed.

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