Toward a quantitative evaluation of Lewis acid strength. A 13CNMR study of the interaction of boron trifluoride with diethyl ether1Dedicated to the memory of Russell S. Drago.1

Journal of Molecular Catalysis A Chemical ◽

10.1016/s1381-1169(98)00127-7 ◽

1999 ◽

Vol 137 (1-3) ◽

pp. 213-221 ◽

Author(s):

Dan Fǎrcaşiu ◽

Povilas Lukinskas ◽

Anca Ghenciu ◽

Rebecca Martin

Keyword(s):

Quantitative Evaluation ◽

Boron Trifluoride ◽

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Polyvinylpolypyrrolidone-supported boron trifluoride: a high-loaded, polymer-supported Lewis acid for the Ritter reaction

Monatshefte für Chemie - Chemical Monthly ◽

10.1007/s00706-008-0007-4 ◽

2008 ◽

Vol 140 (1) ◽

pp. 53-56 ◽

Author(s):

Moslem Mansour Lakouraj ◽

Masoud Mokhtary

Keyword(s):

Boron Trifluoride ◽

Ritter Reaction ◽

Polymer Supported ◽

The Ritter Reaction

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Application of arylboron difluoride Lewis acid catalysts to the Diels-Alder reaction: Convenient, non-volatile alternatives to boron trifluoride

Tetrahedron ◽

10.1016/s0040-4020(99)00472-x ◽

1999 ◽

Vol 55 (28) ◽

pp. 8547-8554 ◽

Author(s):

Maria Fé de la Torre ◽

M.Cruz Caballero ◽

Andrew Whiting

Keyword(s):

Boron Trifluoride ◽

Alder Reaction ◽

Diels Alder ◽

Acid Catalysts ◽

Lewis Acid Catalysts ◽

Diels Alder Reaction

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Empirical Lewis acid strengths for 135 cations bonded to oxygen

Acta Crystallographica Section B Structural Science Crystal Engineering and Materials ◽

10.1107/s2052520617010988 ◽

2017 ◽

Vol 73 (5) ◽

pp. 956-961 ◽

Author(s):

Olivier Charles Gagné ◽

Frank Christopher Hawthorne

Keyword(s):

Strong Correlation ◽

Ionization Energy ◽

Acid Strength ◽

New and updated Lewis acid strengths are listed for 135 cations bonded to oxygen for use with published Lewis base strengths. A strong correlation between Lewis acid strength and ionization energy is shown, and correlation with electronegativity is confirmed.

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INFRARED SPECTRA OF 2,6-DIMETHYL-4-PYRONE COMPLEXES

Canadian Journal of Chemistry ◽

10.1139/v61-150 ◽

1961 ◽

Vol 39 (6) ◽

pp. 1184-1189 ◽

Author(s):

Denys Cook

Keyword(s):

Complex Formation ◽

Oxygen Atom ◽

Carbonyl Group ◽

Frequency Band ◽

Infrared Spectra ◽

Carbonyl Oxygen ◽

Acid Strength ◽

The infrared spectra of 2,6-dimethyl-4-pyrone in solution, and in complexes with HgCl2, ZnCl2, BF3, SbCl5, and HBr have been recorded. A band at 1639 cm−1 in the free pyrone moves to progressively lower frequencies in the complexes as the Lewis acid strength increases, identifying this band as the carbonyl stretching frequency and the donor site as the carbonyl group. A higher-frequency band, at 1678 cm−1 in the free pyrone, moves to lower frequency on complex formation, but to a much smaller extent, and is to be identified with a stretching mode of the ring. The site of protonation in 2,6-dimethyl-4-pyrone salts has been unequivocally shown to be the carbonyl oxygen atom.

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Electronegativity and Lewis acid strength

Journal of the American Chemical Society ◽

10.1021/ja00165a023 ◽

1990 ◽

Vol 112 (9) ◽

pp. 3401-3403 ◽

Author(s):

I. D. Brown ◽

A. Skowron

Keyword(s):

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Boron trifluoride etherate on alumina-modified lewis acid reagent(III): Synthesis of 5-alkyl-3-(1-thioxolanyl-cyclohexenyl)-resorcinol derivatives

Archives of Pharmacal Research ◽

10.1007/bf02973976 ◽

1992 ◽

Vol 15 (1) ◽

pp. 5-8

Author(s):

Seung-Hwa Baek ◽

Chang-Joon Lee

Keyword(s):

Boron Trifluoride ◽

Boron Trifluoride Etherate ◽

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ChemInform Abstract: Electronegativity and Lewis Acid Strength.

10.1002/chin.199033001 ◽

1990 ◽

Vol 21 (33) ◽

Author(s):

I. D. BROWN ◽

A. SKOWRON

Keyword(s):

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Quantitative aspects of Lewis acidity. Part VIII. The validity of infrared carbonyl shifts as measures of Lewis acid strength. The interaction of Lewis acids and phenalen-1-one(perinaphthenone)

Journal of the Chemical Society B Physical Organic ◽

10.1039/j29670000723 ◽

1967 ◽

pp. 723 ◽

Author(s):

Ali Mohammad ◽

D. P. N. Satchell ◽

R. S. Satchell

Keyword(s):

Lewis Acids ◽

Acid Strength ◽

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ChemInform Abstract: Boron Trifluoride Etherate on Alumina. A Modified Lewis Acid Reagent. Part 5. A Convenient Single-Step Synthesis of Cannabinoids.

10.1002/chin.199546228 ◽

2010 ◽

Vol 26 (46) ◽

pp. no-no

Author(s):

S.-H. BAEK ◽

C. N. YOOK ◽

D. S. HAN

Keyword(s):

Boron Trifluoride ◽

Boron Trifluoride Etherate ◽

Single Step ◽

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ChemInform Abstract: Boron Trifluoride Etherate on Alumina-a Modified Lewis Acid Reagent. Part 2. Alkylation of 5-(1,1-Dimethylheptyl)resorcinols.

10.1002/chin.199235109 ◽

2010 ◽

Vol 23 (35) ◽

pp. no-no

Author(s):

S.-H. BAEK ◽

H.-J. KIM

Keyword(s):

Boron Trifluoride ◽

Boron Trifluoride Etherate ◽

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