[Na8Zn4(CH3CO2)16·2H2O]n: two-dimensional sheet-like coordination polymer with strong blue emission

2002 ◽  
Vol 5 (5) ◽  
pp. 361-365 ◽  
Author(s):  
Lei Z. Zhang ◽  
Peng Cheng ◽  
Wei Shi ◽  
Dai-Zheng Liao ◽  
Ying Xiong ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Blue Emission ◽  
Two Dimensional ◽  
Strong Blue Emission

A new two-dimensional folding sheet-like coordination polymer assembled from cadmium(II) and (S)-2-(benzylamino)succinic acid: synthesis, structure and properties

2021 ◽  
Vol 77 (12) ◽  
Author(s):  
Yan Liu ◽  
Hong-Tao Zhang
Keyword(s):  
Coordination Polymer ◽  
Succinic Acid ◽  
Title Compound ◽  
Blue Emission ◽  
Acid Synthesis ◽  
Side Chain ◽  
Solvothermal Reaction ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Carboxylate Groups

A new two-dimensional (2D) coordination polymer, namely, poly[[diaqua[μ3-(S)-2-(benzylamino)succinato-κ4 N,O 1:O 1′:O 4]cadmium(II)] monohydrate], {[Cd(C11H11NO4)(H2O)2]·H2O} n , has been synthesized by the solvothermal reaction of Cd(CH3COO)2·2H2O with the synthesized ligand (S)-2-(benzylamino)succinic acid (H2 L). The title compound has been structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction analysis. In the crystal structure, each CdII cation binds to three carboxylate groups from three symmetry-related L 2− dianions. The tetradentate L 2− ligand links three symmetry-related CdII cations into a 2D folding sheet, which can be simplified as a uninodal (3,3)-connected hcb net with the point symbol (63). In the lattice, all the folding sheets are arranged in an interdigitated fashion and aggregate into zipper-like arrays through interlayer π–π interactions. The large and nonpolar side chain may play an important role in the formation and aggregation of the 2D sheet. The thermal stability and photoluminescence properties of the title compound were investigated, and it exhibits a blue emission with a quantum yield of 8%.

A novel unexpected two-dimensional layer-like luminescent dysprosium coordination polymer [Dy2(phth)3H2O]n by hydrothermal synthesis

2004 ◽  
Vol 82 (12) ◽  
pp. 1745-1751 ◽  
Author(s):  
Yi-Shan Song ◽  
Bing Yan ◽  
Zhen-Xia Chen
Keyword(s):  
Hydrothermal Synthesis ◽  
Coordination Polymer ◽  
Emission Intensity ◽  
Coordination Mode ◽  
Hydrothermal Process ◽  
Blue Emission ◽  
Yellow Emission ◽  
Two Dimensional ◽  
Potassium Acid Phthalate ◽  
Acid Phthalate

Assembling potassium acid phthalate (KHphth) and dysprosium nitrate, a novel luminescent two-dimensional layer-like dysprosium coordination polymer with the formula [Dy2(phth)3H2O]n has been synthesized by a hydrothermal process. It is unexpected that the complex exhibits a new coordination mode with phthalate and an asymmetrical structure for the two dysprosium fragments in the molecular unit. The title coordination polymer crystallizes in the mono clinic system, space group P21/c, with lattice parameters a = 7.913(2) Å, b = 26.360(7) Å, c = 11.563(3) Å, β = 106.864(3)°, V = 2308.3(11) Å3, Dc = 2.404 Mg/m3, Z = 4, F(000) = 1576, GOF = 1.079, R1 = 0.0282. The luminescence spectrum shows that the blue emission intensity of the 4F9/2 → 6H15/2 transition is stronger than the yellow emission intensity of the 4F9/2 → 6H13/2 transition. Key words: dysprosium (III), two-dimensional layer-like coordination polymer, molecular structure, luminescence, hydrothermal synthesis.

High aspect ratio, processable coordination polymer gel nanotubes based on an AIE-active LMWG with tunable emission

2015 ◽  
Vol 51 (78) ◽  
pp. 14678-14681 ◽  
Author(s):  
Venkata M. Suresh ◽  
Anangsha De ◽  
Tapas Kumar Maji
Keyword(s):  
Coordination Polymer ◽  
Aspect Ratio ◽  
Metal Ions ◽  
High Aspect Ratio ◽  
Self Assembly ◽  
Blue Emission ◽  
The Other ◽  
Polymer Gel ◽  
Strong Blue Emission ◽  
Tunable Emission

Self-assembly of a rationally designed AIE active LMWG, driven by intermolecular H-bonding, forms 1D nanofibers with strong cyan emission due to AIE properties of the TPE core. On the other hand, addition of metal ions results in the formation of nanotubular structures with strong blue emission in the gel state due to AIE and MCIE.

A spin-crossover phenomenon in a 2D heterometallic coordination polymer with [Pd(SCN)4]2− building blocks

2021 ◽  
Vol 50 (12) ◽  
pp. 4152-4158
Author(s):  
Kai-Ping Xie ◽  
Si-Guo Wu ◽  
Long-Fei Wang ◽  
Guo-Zhang Huang ◽  
Zhao-Ping Ni ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Building Blocks ◽  
Two Dimensional ◽  
Heterometallic Coordination Polymer

The first spin-crossover example of a two-dimensional coordination polymer containing [Pd(SCN)4]2− building blocks was explored.

Thermally Stable Copper(II)-Doped Cesium Lead Halide Perovskite Quantum Dots with Strong Blue Emission

2019 ◽  
Vol 10 (5) ◽  
pp. 943-952 ◽  
Author(s):  
Chenghao Bi ◽  
Shixun Wang ◽  
Qiang Li ◽  
Stephen V. Kershaw ◽  
Jianjun Tian ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Blue Emission ◽  
Thermally Stable ◽  
Perovskite Quantum Dots ◽  
Strong Blue Emission ◽  
Halide Perovskite ◽  
Lead Halide

scholarly journals Crystal structure of two-dimensional coordination polymer poly-[μ2-azido-aqua-(μ2-pyrazine-2-carboxylato-κ3O,N:N′)nickel(II)], C5H5N5O3Ni

2016 ◽  
Vol 231 (4) ◽  
pp. 1163-1164
Author(s):  
Yu Youzhu ◽  
Guo Yuhua ◽  
Yang Liguo ◽  
Niu Yongsheng
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Two Dimensional

AbstractC5H5N5O3Ni, monoclinic, C2/c (no. 15), a = 8.5804(17) Å, b = 13.790(3) Å, c = 13.969(3) Å, β = 104.37(3)°, V =1601.2(6)Å3, Z = 8, Rgt(F) = 0.0203, wRref(F2) = 0.0550, T = 293 K.

A two-dimensional CdII coordination polymer with 2,2′-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands

2014 ◽  
Vol 70 (5) ◽  
pp. 517-521
Author(s):  
Yu-Xiu Jin ◽  
Fang Yang ◽  
Li-Min Yuan ◽  
Chao-Guo Yan ◽  
Wen-Long Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Phen Ligand ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Carboxylate Groups ◽  
Phenanthroline Ligand ◽  
Phenanthroline Ligands

In poly[[μ3-2,2′-(disulfanediyl)dibenzoato-κ5 O:O,O′:O′′,O′′′](1,10-phenanthroline-κ2 N,N′)cadmium(II)], [Cd(C14H8O4S2)(C12H8N2)] n , the asymmetric unit contains one CdII cation, one 2,2′-(disulfanediyl)dibenzoate anion (denoted dtdb2−) and one 1,10-phenanthroline ligand (denoted phen). Each CdII centre is seven-coordinated by five O atoms of bridging/chelating carboxylate groups from three dtdb2− ligands and by two N atoms from one phen ligand, forming a distorted pentagonal–bipyramidal geometry. The CdII cations are bridged by dtdb2− anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture via a combination of aromatic C—H...π and π–π interactions. The thermogravimetric and luminescence properties of this compound were also investigated.

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