Recent Advances on Rotational Spectroscopy and Microwave Spectroscopic Techniques

2014 ◽  
Vol 42 (9) ◽  
pp. 1369-1378 ◽  
Author(s):  
Li LI ◽  
Ming SUN ◽  
Xiao-Hua LI ◽  
Zhen-Wen ZHAO ◽  
Hui-Min MA ◽  
...  
2019 ◽  
Vol 57 (1) ◽  
pp. 79-112 ◽  
Author(s):  
Susanna L. Widicus Weaver

The recent advancements in far-infrared (far-IR) astronomy brought about by the Herschel, SOFIA, and ALMA observatories have led to technological advancements in millimeterwave and submillimeterwave laboratory spectroscopy that is used to support molecular observations. This review gives an overview of rotational spectroscopy and its relationship with observational astronomy, as well as an overview of laboratory spectroscopic techniques focusing on both historical approaches and new advancements. Additional topics discussed include production and detection techniques for unstable molecular species of astrochemical interest, data analysis approaches that address spectral complexity and line confusion, and the current state of and limitations to spectral line databases. Potential areas for new developments in this field are also reviewed. To advance the field, the following challenges must be addressed: ▪ Data acquisition speed, spectral sensitivity, and analysis approaches for complex mixtures and broadband spectra are the greatest limitations—and hold the greatest promise for advancement—in this field of research. ▪ Full science return from far-IR observatories cannot be realized until laboratory spectroscopy catches up with the data rate for observations. ▪ New techniques building on those used in the microwave and IR regimes are required to fill the terahertz gap.


Nanophotonics ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 19-37 ◽  
Author(s):  
Timea Frosch ◽  
Andreas Knebl ◽  
Torsten Frosch

AbstractInnovations in Raman spectroscopic techniques provide a potential solution to current problems in pharmaceutical drug monitoring. This review aims to summarize the recent advances in the field. The developments of novel plasmonic nanoparticles continuously push the limits of Raman spectroscopic detection. In surface-enhanced Raman spectroscopy (SERS), these particles are used for the strong local enhancement of Raman signals from pharmaceutical drugs. SERS is increasingly applied for forensic trace detection and for therapeutic drug monitoring. In combination with spatially offset Raman spectroscopy, further application fields could be addressed, e.g. in situ pharmaceutical quality testing through the packaging. Raman optical activity, which enables the thorough analysis of specific chiral properties of drugs, can also be combined with SERS for signal enhancement. Besides SERS, micro- and nano-structured optical hollow fibers enable a versatile approach for Raman signal enhancement of pharmaceuticals. Within the fiber, the volume of interaction between drug molecules and laser light is increased compared with conventional methods. Advances in fiber-enhanced Raman spectroscopy point at the high potential for continuous online drug monitoring in clinical therapeutic diagnosis. Furthermore, fiber-array based non-invasive Raman spectroscopic chemical imaging of tablets might find application in the detection of substandard and counterfeit drugs. The discussed techniques are promising and might soon find widespread application for the detection and monitoring of drugs in various fields.


1988 ◽  
Vol 143 ◽  
Author(s):  
J. L. Erskine ◽  
C. A. Ballentine ◽  
Jose Araya-Pochet ◽  
Richard Fink

AbstractNew opportunities for research on magnetic materials are emerging as a result of quiet revolutions in several areas including: materials synthesis techniques, surface characterization capabilities, new magnetic sensitive detectors and spectroscopic techniques, improved synchrotron radiation instrumentation, and predictive modeling based on first principals calculations. This paper describes some of the more recent advances and assesses some of the new opportunities that are emerging in the field of magnetic materials research.


2019 ◽  
Vol 48 (22) ◽  
pp. 5432-5453 ◽  
Author(s):  
Li Zhang ◽  
Tao Qian ◽  
Xingyu Zhu ◽  
Zhongli Hu ◽  
Mengfan Wang ◽  
...  

Recent advances in optimal design of lithium–sulfur batteries with the aid of in situ optical spectroscopic techniques, including Raman, infrared and ultraviolet-visible spectroscopies, are systematically summarized.


1988 ◽  
Vol 132 ◽  
pp. 525-530
Author(s):  
Raffaele G. Gratton

The use CCD detectors has allowed a major progress in abundance derivations for globular cluster stars in the last years. Abundances deduced from high dispersion spectra now correlates well with other abundance indicators. I discuss some problems concerning the derivation of accurate metal abundances for globular clusters using high dispersion spectra from both the old photographic and the most recent CCD data. The discrepant low abundances found by Cohen (1980), from photographic material for M71 giants, are found to be due to the use of too high microturbulences.


Author(s):  
Marcos F. Maestre

Recently we have developed a form of polarization microscopy that forms images using optical properties that have previously been limited to macroscopic samples. This has given us a new window into the distribution of structure on a microscopic scale. We have coined the name differential polarization microscopy to identify the images obtained that are due to certain polarization dependent effects. Differential polarization microscopy has its origins in various spectroscopic techniques that have been used to study longer range structures in solution as well as solids. The differential scattering of circularly polarized light has been shown to be dependent on the long range chiral order, both theoretically and experimentally. The same theoretical approach was used to show that images due to differential scattering of circularly polarized light will give images dependent on chiral structures. With large helices (greater than the wavelength of light) the pitch and radius of the helix could be measured directly from these images.


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