scholarly journals The Role of Inorganic Oxide Supports in Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides

2012 ◽  
Vol 33 (2-3) ◽  
pp. 416-424 ◽  
Author(s):  
Ting CAO ◽  
Liting SUN ◽  
Yu SHI ◽  
Li HUA ◽  
Ran ZHANG ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonates ◽  
Oxide Supports ◽  
Inorganic Oxide

Chemical fixation of CO2 into cyclic carbonates catalyzed by bimetal mixed MOFs: the role of the interaction between Co and Zn

2020 ◽  
Vol 49 (2) ◽  
pp. 312-321 ◽  
Author(s):  
Yuanfeng Wu ◽  
Xianghai Song ◽  
Siquan Xu ◽  
Yuan Chen ◽  
Olayinka Oderinde ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Conversion ◽  
Chemical Fixation ◽  
Cyclic Carbonates

Catalytic conversion of carbon dioxide into cyclic carbonates in the presence of bimetal mixed MOFs.

scholarly journals Synthesis of cyclic carbonates by ruthenium(VI) bis-imido porphyrin/TBACl-catalyzed reaction of epoxide with CO2

2020 ◽  
Vol 24 (05n07) ◽  
pp. 809-816
Author(s):  
Caterina Damiano ◽  
Paolo Sonzini ◽  
Daniela Intrieri ◽  
Emma Gallo
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Nitrogen Atom ◽  
Binary System ◽  
Cyclic Carbonate ◽  
Mechanistic Study ◽  
Cyclic Carbonates ◽  
Experimental Conditions ◽  
Positive Role

The catalytic activity of the ruthenium(VI) bis-imido porphyrin complex/TBACl binary system in promoting the CO[Formula: see text] cycloaddition to epoxides forming cyclic carbonates is here reported. The system was very efficient in catalyzing the conversion of differently substituted epoxides under mild experimental conditions (100 [Formula: see text]C and 0.6 MPa of CO[Formula: see text]. Even if the sole TBACl resulted active under the optimized experimental conditions, the addition of ruthenium species was fundamental to maximizing the reaction productivity both in terms of epoxide conversions and cyclic carbonate selectivities. A preliminary mechanistic study indicated a positive role of ruthenium imido nitrogen atom in activating carbon dioxide.

The role of substituents of chlorostannoxanes on the reactivity of the catalysts during the synthesis of cyclic carbonates using epoxides and carbon dioxide

2012 ◽  
Vol 2 (1) ◽  
pp. 66-74 ◽  
Author(s):  
Sharon Pulla ◽  
Punnamchandar Ramidi ◽  
Benjamin L. Jarvis ◽  
Pradip Munshi ◽  
William O. Griffin ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Carbonates

Insights into the Solubility of Carbon Dioxide in Grafted Mesoporous Silica for the Catalytic Synthesis of Cyclic Carbonates by Nanoconfinement

2021 ◽  
Author(s):  
Shahab Boroun ◽  
Abolfazl Alizadeh Sahraei ◽  
Abdol Hadi Mokarizadeh ◽  
Houshang Alamdari ◽  
Frédéric-Georges Fontaine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mesoporous Silica ◽  
Catalytic Synthesis ◽  
Cyclic Carbonates

Unraveling the Role of Zinc on Bimetallic Fe5C2–ZnO Catalysts for Highly Selective Carbon Dioxide Hydrogenation to High Carbon α-Olefins

ACS Catalysis ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 2121-2133
Author(s):  
Chao Zhang ◽  
Chenxi Cao ◽  
Yulong Zhang ◽  
Xianglin Liu ◽  
Jing Xu ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Carbon ◽  
Carbon Dioxide Hydrogenation

Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers

2020 ◽  
Vol 40 ◽  
pp. 156-170 ◽  
Author(s):  
Ping Shao ◽  
Luocai Yi ◽  
Shumei Chen ◽  
Tianhua Zhou ◽  
Jian Zhang
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Metal Organic Frameworks ◽  
Metal Centers ◽  
Metal Organic
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