scholarly journals Carbon isotopic composition of shale gas in the Silurian Longmaxi Formation of the Changning area, Sichuan Basin

2016 ◽  
Vol 43 (5) ◽  
pp. 769-777 ◽  
Author(s):  
Ziqi FENG ◽  
Dan LIU ◽  
Shipeng HUANG ◽  
Wei WU ◽  
Dazhong DONG ◽  
...  
2016 ◽  
Vol 36 (1) ◽  
pp. 102-111
Author(s):  
Jin-ning Peng ◽  
Dong-yan Wang ◽  
Guang-xiang Liu ◽  
Min Zhang ◽  
Feng-li Li

Energies ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5981
Author(s):  
Chunhui Cao ◽  
Liwu Li ◽  
Yuhu Liu ◽  
Li Du ◽  
Zhongping Li ◽  
...  

The Weiyuan (WY) and Changning (CN) fields are the largest shale gas fields in the Sichuan Basin. Though the shale gases in both fields are sourced from the Longmaxi Formation, this study found notable differences between them in molecular composition, carbon isotopic composition, and noble gas abundance and isotopic composition. CO2 (av. 0.52%) and N2 (av. 0.94%) were higher in Weiyuan than in Changning by an average of 0.45% and 0.70%, respectively. The δ13C1 (−26.9% to −29.7%) and δ13C2 (−32.0% to −34.9%) ratios in the Changning shale gases were about 8% and 6% heavier than those in Weiyuan, respectively. Both shale gases had similar 3He/4He ratios but different 40Ar/36Ar ratios. These geochemical differences indicated complex geological conditions and shed light on the evolution of the Lonmaxi shale gas in the Sichuan Basin. In this study, we highlight the possible impacts on the geochemical characteristics of gas due to tectonic activity, thermal evolution, and migration. By combining previous gas geochemical data and the geological background of these natural gas fields, we concluded that four factors account for the differences in the Longmaxi Formation shale gas in the Sichuan Basin: a) A different ratio of oil cracking gas and kerogen cracking gas mixed in the closed system at the high over-mature stage. b) The Longmaxi shales in WY and CN have had differential geothermal histories, especially in terms of the effects from the Emeishan Large Igneous Province (LIP), which have led to the discrepancy in evolution of the shales in the two areas. c) The heterogeneity of the Lower Silurian Longmaxi shales is another important factor, according to the noble gas data. d) Although shale gas is generated in closed systems, natural gas loss throughout geological history cannot be avoided, which also accounts for gas geochemical differences. This research offers some useful information regarding the theory of shale gas generation and evolution.


2015 ◽  
Vol 3 (2) ◽  
pp. SJ35-SJ47 ◽  
Author(s):  
Qingyan Tang ◽  
Mingjie Zhang ◽  
Chunhui Cao ◽  
Zhe Song ◽  
Zhongping Li ◽  
...  

We have developed a vacuum-crushing method for the extraction of gases stored in shale for the determination of gas yield, chemical composition, and carbon isotopic composition by online gas-chromatography and mass spectrometry. Analysis of the evacuation and parallel experiments showed low standard deviation and good reproducibility. This approach significantly improved the detection limits for trace-gas analysis in shale and measured multiple nonhydrocarbon gas components in a single run. We analyzed the chemical and carbon isotopic compositions of the gases released by one-step vacuum crushing from nineteen samples of organic-rich Longmaxi Formation (Fm.) shale in Changning outcrop, Sichuan Basin, China, and we studied the main controls on gas chemistry of retained gas in the Longmaxi Shale. The results showed that the crushed gas is high in [Formula: see text] and [Formula: see text] but low in [Formula: see text]. The crushed gas has obviously lower [Formula: see text] ratios than the gas produced from the Longmaxi Fm. after hydraulic fracturing; it was dominated by [Formula: see text] gas while it is normalized to 100% total gaseous hydrocarbons and similar in chemical composition to hydrocarbon gases in the produced gas. Yields of [Formula: see text], [Formula: see text], and [Formula: see text] in the crushed gas of most samples showed a weak positive correlation with total organic carbon (TOC) contents. The crushed gas had significantly light [Formula: see text] (on average [Formula: see text]) values and similar [Formula: see text] values when compared with the produced gas in the Changning area. The [Formula: see text] values of [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text] have similar features to the produced gas from the Weiyuan shale-gas play. Isotopically reversed trends ([Formula: see text]) between ethane and methane were observed for some samples. Our findings regarding the similarity in chemical and carbon isotopic compositions between crushed gas and produced gas from the Weiyuan shale-gas play might provide important evidence of the origin and storage of shale gas in the organic-rich Silurian Longmaxi Fm.


2016 ◽  
Vol 20 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Keke Huang ◽  
Xiaoning Li ◽  
Zuowei Hu ◽  
Yijiang Zhong

<p>The late Permian thermal events related to Emeishan Basalt has made a great impact on the underlying carbonate rock properties in the western margin of the Yangtze Platform. In this paper, we investigate the carbon and oxygen isotopic composition of the Qixia Formation carbonates from two sections: the Qiaoting Section in the northeastern part of the Sichuan Basin and the Changjianggou Section at the northwestern edge of the Basin. The data reveal that: (i) Samples from Qiaoting section show a relatively narrow range of δ<sup>13</sup>C and δ<sup>18</sup>O, varying from 2.7‰ to 5.2‰ with an average of 4.2‰, and -3.8‰ to -7.8‰ with an average of -5.4‰, respectively. In contrast, Samples from Changjianggou section exhibit larger magnitude of variation in δ<sup>13</sup>C and δ<sup>18</sup>O, ranging from -1‰ to 3.8‰ with an average of 1.5‰, and -2.1 to -9.2‰, with an average of -6.0‰ respectively; (ii) δ<sup>13</sup>C and δ<sup>18</sup>O records in carbonates from Qiaoting section are similar to those of Middle Permian seawater whereas carbonates from the Changjianggou section are depleted in <sup>13</sup>C and <sup>18</sup>O compared to contemporary seawater; (iii) On the basis of combined petrographic and paleo-heat flow evidence, the lower carbon and oxygen isotopic composition of the carbonates from the Changjianggou section are interpreted to be the results of thermal effects of Emeishan Basalt because of its proximity to the eruption center of the basalt. The high temperature reduced the δ<sup>18</sup>O values of the carbonates and forced the organic matter to mature at an early stage, thus producing <sup>13</sup>C-enriched carbon dioxide to participate in the formation of carbonates.  </p><p> </p><p><strong>Composición Isotópica de Oxígeno y Carbón en Rocas de Carbonato de la Formación de Edad Pérmica Qixia, en la Cuenca de Sichuan: Efectos Térmicos del Basalto Emeishan  </strong></p><p><strong><br /></strong></p><p><strong>Resumen</strong></p><p>Los eventos térmicos del Pérmico tardío relacionados con el Basalto Emeishan han tenido un gran impacto en las propiedades de las rocas de carbonato subyacentes en el margen occidental de la plataforma Yangtze. En este artículo se investiga la composición isotópica de carbonatos de la formación Qixia en dos secciones: la sección de Qiaoting en la parte nororiental de la cuenca Sichuan y la sección Changjianggou, en el noroccidente de la cuenca. La información evidencia que, (i) las muestras de la sección Qiaoting tienen un espectro más angosto que va de δ<sup>13</sup>C a δ<sup>18</sup>O, con variación de 2.7 ‰ a 5,2 ‰, con un promedio de 4.2 ‰, y -3.8 ‰ a -7.8 ‰, con una media de -5.4 ‰, respectivamente. En contraste, las muestras de la sección Changjianggou tienen una variación de mayor magnitud en δ<sup>13</sup>C a δ<sup>18</sup>O que va desde -1 ‰ hasta 3.8 ‰, con un promedio de 1.5 ‰, y de -2.1 a -9.2 ‰, con una media de -6.0 ‰, respectivamente; (ii) los registros de δ<sup>13</sup>C y δ<sup>18</sup>O en carbonatos son similares a los de agua marina del pérmico medio, mientras que los carbonatos de la sección Changjianggou se ven empobrecidos en 13C y 18O comparados al agua marina de esta edad; con base en la petrografía combinada y la evidencia del flujo paleotérmico, la baja composición isotópica de oxígeno y carbón de los carbonatos en la sección de Changjianggou se interpretó como resultado de los efectos térmicos del Basalto Emeishan debido a la proximidad con el centro de erupción. La alta temperatura redujo los valores de δ<sup>18</sup>O de los carbonatos y llevó a la maduración temprana de la materia orgánica, lo que produjo dióxido de carbono enriquecido en <sup>13</sup>C durante la formación de los carbonatos.</p>


2018 ◽  
Vol 89 ◽  
pp. 27-37 ◽  
Author(s):  
Mingjie Zhang ◽  
Qingyan Tang ◽  
Chunhui Cao ◽  
Zonggang Lv ◽  
Tongwei Zhang ◽  
...  

2016 ◽  
Vol 1 (2) ◽  
pp. 147-155 ◽  
Author(s):  
Zhenya Qu ◽  
Jianan Sun ◽  
Jianting Shi ◽  
Zhaowen Zhan ◽  
Yanrong Zou ◽  
...  

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