Carbon and oxygen stable isotope record of upper Kimmeridgian shallow-marine ramp carbonates (Iberian Basin, NE Spain): the imprint of different burial and tectonic histories

Bulk carbon and oxygen stable isotopes of ancient shallow-marine carbonates can record the effects of multiple palaeoenvironmental factors, but also the imprint of several post-depositional processes, which may alter the original marine isotopic composition. In this study, carbon and oxygen stable isotope analyses were performed on bulk carbonate, bivalve calcitic-shell (Trichites) and calcite vein samples from two stratigraphic sections (Tosos and Fuendetodos, present-day distance 15km), representing proximal inner- and distal mid-ramp environments, respectively, of the uppermost Kimmeridgian ramp facies deposited in the northern Iberian Basin (NE Spain). These successions underwent different diagenetic pathways that altered the primary marine isotopic composition in each section in different ways. Different burial histories, tectonic uplift and a variable exposure to meteoric diagenesis from the end of the Kimmeridgian to the Cenozoic (following Alpine tectonic uplift) are reflected in the different alteration patterns of the carbon and oxygen stable isotope signatures. A significant deviation to lower values in both δ13O and δ18O is recorded in those carbonates mostly exposed to meteoric diagenesis (distal mid-ramp Fuendetodos section), because of post-depositional tectonic uplift (telogenesis). On the other hand, the deposits mainly affected by burial diagenesis (proximal inner-ramp Tosos section) only record low δ18O with respect to expected values for pristine Kimmeridgian marine carbonates. The different burial and tectonic uplift histories of these deposits in each sector, due to their different tectonic evolution in this part of the basin, resulted in a variable degree of diagenetic resetting. However, in spite of the different diagenetic resetting reported of the carbon and oxygen stable isotope signatures in each section, these carbonates show similar cement types in termsof fabrics and cathodoluminescence properties. The diagenetic resetting reported for these carbonates prevents the use of the δ13O and δ18O records for addressing palaeoenvironmental interpretations, but instead highlights useful features regarding the variable diagenetic overprint of the studied shallow-marine carbonate successions concerning their specific post-depositional history.

MARINE BIOGENIC CARBONATES AND RADIOCARBON—A RETROSPECTIVE ON SHELLS AND CORALS WITH AN OUTLOOK ON CHALLENGES AND OPPORTUNITIES

ABSTRACT Many organisms living in the ocean create tests, shells, or related physical structures of calcium carbonate (CaCO3). As this is most often from dissolved inorganic carbon, using organisms that create calcium carbonate structures for climate research and dating purposes requires knowledge of the origin of carbon that is incorporated. Here, we give a short overview of research on marine carbonates over the last 60 years, especially that based on shell and coral samples. Both shells and corals exhibit annual growth patterns, like trees, and therefore offer possibilities for yearly resolution of past radiocarbon (14C) variations. We concentrate on their evolution in 14C dating including difficulties in determining reservoir ages as well as the possibilities they offer for archaeological dating, oceanography, calibration purposes as well as environmental research in general.

Calcium isotope compositions as a means to trace carbonate recycling

Marine carbonate, an important CO2 reservoir, is continuously sent to the Earth's deep interior at subduction zones, forming an essential part of the global carbon cycle. The pros and cons of using calcium isotope compositions to trace marine carbonates recycled into the mantle are discussed in this Perspective.

Age, microfacies and depositional environment of the Middle to Late Paleocene shallow-marine carbonates in the Sirt Basin of Libya (Upper Sabil Formation): “Are Intisar domal structures pinnacle reefs?”

In the central-eastern Sirt Basin, enigmatic Intisar domal structures host significant hydrocarbon accumulations. These structures have been commonly interpreted as pinnacle reefs/bioherms occurring in the open-marine basinal environment. Generally, pinnacle reefs/bioherms are mainly characterized by in situ carbonates. The current study challenges the Intisar pinnacle reef/bioherm model by examining one of the domal structures in terms of biostratigraphy, microfacies and depositional environment. These structures were dated using larger benthic foraminifera, which yielded a Middle to Late Paleocene age (Selandian–Early Thanetian). Thirteen microfacies types representing different carbonate ramp environments ranging from outer ramp to inner ramp, were defined. Outer ramp deposits have been observed adjacent to the domal structure, represented mainly by wackestone with small benthic and planktonic foraminifera. The outer ramp deposits are most likely isochronous to the domal structures. The lower part of the domal structures is composed mainly of foraminiferal–algal–echinodermal packstones. The upper part is characterized by foraminiferal–algal–echinodermal packstones with intercalated microbialite–coral boundstones. The euphotic inner ramp deposits are preserved on the crest of the domal structure, consisting of grainstone and packstone rich in Glomalveolina. As a result of this study, the Intisar domal structures are seen as erosional relics of a carbonate ramp and no evidence for pinnacle reef/bioherm model was found.