Near-field scanning optical microscopy imaging of luminescent polymers

Conjugated polymers such as poly(p-pyridyl vinylene)(PPyV) have interesting photoluminescence and electroluminescence properties. These polymers have a high quantum yield of luminescence and are of great practical importance as light-emitting diodes or organic semiconductors. We have performed studies on thin films(about 50nm) of these polymers using the high spatial optical resolution of NSOM.The luminescent polymer film was excited with 488nm light and the fluorescence was collected with a high numerical aperture microscope objective. Topography and NSOM fluorescence images were collected simultaneously and used for studying the morphology and optical properties of the film. An example of topography and fluorescence NSOM images of the film is shown in Fig. 1a. The films are very flat (2nm rms variations in topography) and have very few features. The NSOM fluorescence image shows great film inhomogeneity with bright features varying in size from 80-250nm observed throughout (Fig. 1b). These features do not correlate with the topography, indicating they may be located in the bulk of the polymer or are simply not resolvable in the topography image.