Digital simulation of homogeneous chemical reactions coupled to heterogeneous electron transfer and applications at platinum/mica/platinum ultramicroband electrodes

1987 ◽  
Vol 59 (17) ◽  
pp. 2101-2111 ◽  
Author(s):  
Theresa Varco. Shea ◽  
Allen J. Bard
Keyword(s):  
Electron Transfer ◽  
Chemical Reactions ◽  
Digital Simulation ◽  
Heterogeneous Electron Transfer ◽  
Homogeneous Chemical

Possible use of chronopotentiometry at the interface between two immiscible liquid phases to the studies of homogeneous chemical reactions

1985 ◽  
Vol 50 (8) ◽  
pp. 1636-1641
Author(s):  
Emanuel Makrlík
Keyword(s):  
Electron Transfer ◽  
Chemical Reactions ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Immiscible Liquid ◽  
Liquid Phases ◽  
Homogeneous Chemical ◽  
The Given ◽  
Galvanostatic Conditions

The theoretical potential-time dependence corresponding to the electron transfer reaction proceeding at the interface between two immiscible liquid phases with the redox pairs O1/R1 in the aqueous (aq) phase and O2/R2 in the non-aqueous (non) phase, that is complicated by the reaction R1(aq) + Z(aq) → O1(aq) in the aqueous phase, has been derived under the galvanostatic conditions. Moreover, a method for the determination of the formal rate constant kf for the given homogeneous chemical reaction is proposed.

Heterogeneous electron transfer as a pathway in the dissolution of magnetite in oxalic acid solutions

1983 ◽  
Vol 22 (16) ◽  
pp. 2224-2226 ◽  
Author(s):  
E. Baumgartner ◽  
M. A. Blesa ◽  
H. Marinovich ◽  
A. J. G. Maroto
Keyword(s):  
Electron Transfer ◽  
Oxalic Acid ◽  
Acid Solutions ◽  
Heterogeneous Electron Transfer
Sign in / Sign up

Export Citation Format

Share Document