SET-LRP of Bio- and Petroleum-Sourced Methacrylates in Aqueous Alcoholic Mixtures

2019 ◽  
Vol 20 (4) ◽  
pp. 1816-1827 ◽  
Author(s):  
Adrian Moreno ◽  
Nabil Bensabeh ◽  
Jaan Parve ◽  
Juan C. Ronda ◽  
Virginia Cádiz ◽  
...  
Keyword(s):  
2010 ◽  
Vol 224 (05) ◽  
pp. 729-742 ◽  
Author(s):  
G. Bandyopadhyay ◽  
S. Dutta ◽  
Sujit Chandra Lahiri

Soft Matter ◽  
2018 ◽  
Vol 14 (45) ◽  
pp. 9243-9249 ◽  
Author(s):  
Marcelo A. da Silva ◽  
Vincenzo Calabrese ◽  
Julien Schmitt ◽  
Duygu Celebi ◽  
Janet L. Scott ◽  
...  

Alcohol-induced gelation of partially oxidised cellulose nanofibrils (OCNFs): nanoscale (SAXS) and macroscale (rheology) insights into OCNF self-assembly in aqueous-alcoholic mixtures.


2003 ◽  
Vol 217 (6) ◽  
pp. 615-636 ◽  
Author(s):  
S. K. Gumtya ◽  
G. Bandyopadhyay ◽  
S. C. Lahiri

AbstractAttempts were made for a critical examination of the use of ΔS°t as a structural probe to study the ion induced perturbations on aquo-alcoholic solvent mixtures. The division of the thermodynamic properties of TATB (tetraphenyl arsonium tetraphenyl borate) in solution into equal parts is not free from defects. Naturally, the calculation of single ion values based on TATB is also problematic. Dissection of the single ion values like TΔS°t(ion) as suggested by Kundu is full of errors. Analysis shows TΔS°t(ion) to be an insensitive parameter to determine the structural characteristics of aquo-alcoholic mixtures. Structure of aquo-alcoholic mixtures should be determined from the excess thermodynamic properties of mixing, excess dielectric properties of mixing, excess polarizabilities, the correlation parameter “g” etc. Other properties like ultrasonic sound absorption, excess volume and viscosity of mixing were found to be useful. Ion induced perturbations of any solvent system will be dictated by the structure of the particular solvent system. A knowledge of the structure of the aquo-alcoholic mixtures is imperative to develop an idea regarding ion induced perturbations as mirror image relations because of compensation of ΔH° and TΔS° (and of ΔH°t and TΔS°t) will be observed in any solvent system. The thermodynamic measurements provide a summary of all interaction energies over a long time. To comprehend the rational structural details of the solvent systems, accurate thermodynamic measurements alongwith relaxation experiments providing high time and good structural resolutions are necessary.


1989 ◽  
Vol 56 (3) ◽  
pp. 521-527 ◽  
Author(s):  
Alice Pierre

SummaryWe have investigated the role of pH in the destabilization of milk and sodium caseinate solutions by ethanol. Ethanol shifted the pH of minimum stability of both caseinate and milk to higher values. A linear relation between this pH and the reciprocal dielectric constant of the mixture was observed. The addition of calcium to these alcoholic mixtures also increased the pH of minimum stability. The results are discussed in terms of the alcohol-induced shifts in the pK values of important constituent amino acids and of the effect of alcohol on soluble Ca levels.


2020 ◽  
Vol 16 (2) ◽  
pp. 207-212
Author(s):  
Wissam Zam ◽  
Ali Ali ◽  
Walaa Ibrahim

Background and Objective: With the significant increase in the prevalence of infectious diseases and the development of drug resistance by human pathogenic bacteria, there is a continuous need to discover new antimicrobial compounds from plants. Methods: Four extracts of wild Myrtus communis L. berries (myrtle berries) were prepared with the addition of Cinnamomum verum and Eugenia caryophyllata. The extracts were screened in vitro for their antimicrobial activities using agar-well diffusion method against Escherichia coli, Staphylococcus aureus, Enterobacter cloacae, Listeria monocytogenes, Pseudomonas aeruginosa and Proteus mirabilis cultures. Results: The inhibition zones ranged from 12 to 22 mm. The MICs values of extracts lies between the ranges of 30 to 100 mg/ml. Of the extracts studied, the most active ones were those obtained from the myrtle berries:cloves, myrtle berries:cinnamon:cloves with the highest inhibition zones 22 mm and 17mm against S. aureus and L. monocytogenes at 50 mg/ml and 80 mg/ml, respectively. None of the extracts was active against E. coli and P. mirabilis. Conclusion: The present investigations have exposed that the myrtle berries:cloves, myrtle berries: cinnamon:cloves extracts could be used in traditional medicine as natural antimicrobial agents in treatment the bacterial infections.


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