Controlling π–π Interactions through Coordination Bond Formation: Assembly of 1-D Chains of acac-Based Coordination Compounds

2021 ◽  
Author(s):  
Rafael León-Zárate ◽  
Jesús Valdés-Martínez
Keyword(s):  
Coordination Compounds ◽  
Bond Formation ◽  
Coordination Bond ◽  
Π Interactions

Influence of N-heteroaromatic π–π stacking on supramolecular assembly and coordination geometry; effect of a single-atom change in the ligand

2015 ◽  
Vol 44 (12) ◽  
pp. 5488-5502 ◽  
Author(s):  
Hamid Reza Khavasi ◽  
Bahareh Mir Mohammad Sadegh
Keyword(s):  
Coordination Compounds ◽  
Crystal Packing ◽  
Supramolecular Assembly ◽  
Single Atom ◽  
Coordination Geometry ◽  
Geometry Effect ◽  
Π Interactions ◽  
Π Stacking ◽  
Nitrogen Heteroatom ◽  
Aromatic Systems

A study on how the polarization of aromatic systems, through the introduction of a nitrogen heteroatom, affects the π–π interactions and crystal packing of mercury coordination compounds.

Paramagnetic–Diamagnetic Phase Transition Accompanied by Coordination Bond Formation–Dissociation in the Dithiolate Complex Na[Ni(pdt)2]·2H2O

2011 ◽  
Vol 50 (14) ◽  
pp. 6405-6407 ◽  
Author(s):  
Shinya Takaishi ◽  
Nozomi Ishihara ◽  
Kazuya Kubo ◽  
Keiichi Katoh ◽  
Brian K. Breedlove ◽  
...  
Keyword(s):  
Phase Transition ◽  
Bond Formation ◽  
Coordination Bond

scholarly journals Chelate ring stacking interactions in the supramolecular assemblies of Zn(ii)and Cd(ii) coordination compounds: a combined experimental and theoretical study

CrystEngComm ◽  
2017 ◽  
Vol 19 (10) ◽  
pp. 1389-1399 ◽  
Author(s):  
Farhad Akbari Afkhami ◽  
Ali Akbar Khandar ◽  
Ghodrat Mahmoudi ◽  
Waldemar Maniukiewicz ◽  
Atash V. Gurbanov ◽  
...  
Keyword(s):  
Coordination Compounds ◽  
Theoretical Study ◽  
Chelate Ring ◽  
Supramolecular Assemblies ◽  
Stacking Interactions ◽  
Π Interactions

We report seven Zn(ii)/Cd(ii) complexes with picolinoyl/isonicotinoyl hydrazone based ligands exhibiting relevant chelate–π interactions.

Coordination Bond Formation at Charge-Transfer Phase Transition in (BDTA)2[Co(mnt)2]

2006 ◽  
Vol 128 (4) ◽  
pp. 1084-1085 ◽  
Author(s):  
Yoshikatsu Umezono ◽  
Wataru Fujita ◽  
Kunio Awaga
Keyword(s):  
Phase Transition ◽  
Charge Transfer ◽  
Bond Formation ◽  
Coordination Bond ◽  
Transfer Phase

scholarly journals O(−)⋯C interactions and bond formation in 1-naphtholate anions with peri-located electrophilic carbon centres

CrystEngComm ◽  
2019 ◽  
Vol 21 (6) ◽  
pp. 1009-1018 ◽  
Author(s):  
Jonathan C. Bristow ◽  
Matthew A. Addicoat ◽  
John D. Wallis
Keyword(s):  
Carbonyl Group ◽  
Bond Formation ◽  
Carbonyl Groups ◽  
X Ray ◽  
Π Interactions ◽  
X Ray Crystallography

n–π* interactions between naphtholate O anions and carbonyl groups are determined to be shorter than in corresponding naphthols by X-ray crystallography, and lead to cyclisations with long O–C bonds when the carbonyl group is replaced by a strongly electron deficient alkene.

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