Selective Hydrogenation of CO2 to Hydrocarbons: Effects of Fe3O4 Particle Size on Reduction, Carburization, and Catalytic Performance

Author(s):  
Junhui Liu ◽  
Kuan Li ◽  
Yakun Song ◽  
Chunshan Song ◽  
Xinwen Guo
2012 ◽  
Vol 550-553 ◽  
pp. 420-423 ◽  
Author(s):  
Qian Wen Dai ◽  
Zi Li Liu ◽  
Cui Xia Xu ◽  
Qi Gang Xie ◽  
Fan Zhang ◽  
...  

The Ni-Mo-P amorphous catalysts were prepared by chemical reduction method under different sonication conditions. The catalytic performance of the prepared catalysts in selective hydrogenation of nitrobenzene(NB) to aniline(AN) were characterized by XRD, BET, N2-adsorption, H2-TPR and H2-TPD. The results show that the introduction of ultrasonic can improve the dispersion of the active sites in the catalyst, the particle size of the catalyst is also smaller than the regular prepared Ni-Mo-P amorphous catalyst. And the influences of the sonication power and time on the catalysts were discussed and compared. The optimal sonication condition is 70 W within 25 min, its optimal reaction time is 150 min.


Author(s):  
Sajjad Rimaz ◽  
Reza Katal

: In the present study, SAPO-34 particles were synthesized using hydrothermal (HT) and dry gel (DG) conversion methods in the presence of diethyl amine (DEA) as an organic structure directing agent (SDA). Carbon nanotubes (CNT) were used as hard template in the synthesis procedure to introduce transport pores into the structures of the synthesized samples. The synthesized samples were characterized with different methods to reveal effects of synthesis method and using hard template on their structure and catalytic performance in methanol to olefin reaction (MTO). DG conversion method results in smaller particle size in comparison with hydrothermal method, resulting in enhancing catalytic performance. On the other side, using CNT in the synthesis procedure with DG method results in more reduction in particle size and formation of hierarchical structure which drastically improves catalytic performance.


2011 ◽  
Vol 103 (2) ◽  
pp. 405-417 ◽  
Author(s):  
Kanda Pattamakomsan ◽  
Francisco Jose Cadete Santos Aires ◽  
Kongkiate Suriye ◽  
Joongjai Panpranot

RSC Advances ◽  
2016 ◽  
Vol 6 (79) ◽  
pp. 75541-75551 ◽  
Author(s):  
Feng Jiang ◽  
Jian Cai ◽  
Bing Liu ◽  
Yuebing Xu ◽  
Xiaohao Liu

Palladium particles of different sizes obtained directly and indirectly by various methods were studied to clarify the particle size effect in the selective hydrogenation of cinnamaldehyde (CAL).


2020 ◽  
Vol 22 (17) ◽  
pp. 5730-5741
Author(s):  
Shuo Chen ◽  
Li-Li Ling ◽  
Shun-Feng Jiang ◽  
Hong Jiang

The defined catalyst (Co@NC) is prepared through the pyrolysis of the Co-centered metal–organic framework (MOF), in which Co active species (Co–Nx, surface Co NPs) and particle size play important roles in the catalytic hydrogenation of aromatic nitro compounds.


2019 ◽  
Vol 9 (6) ◽  
pp. 1329-1333 ◽  
Author(s):  
Fan Yang ◽  
Jingbo Mao ◽  
Shenmin Li ◽  
Jingmei Yin ◽  
Jinxia Zhou ◽  
...  

The synergy of single Co atoms/Co clusters and CoOx nanoparticles, as well as reduced graphene oxide, leads to superior catalytic performance.


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