Effect of Oxygen-Donor Charge on Adjacent Nitrogen-Donor Interactions in Eu3+ Complexes of Mixed N,O-Donor Ligands Demonstrated on a 10-Fold [Eu(TPAMEN)]3+ Chelate Complex

2021 ◽  
Vol 60 (4) ◽  
pp. 2477-2491
Author(s):  
Kathleen Schnaars ◽  
Masashi Kaneko ◽  
Kiyoshi Fujisawa
Keyword(s):  
Chelate Complex ◽  
Donor Ligands ◽  
Oxygen Donor ◽  
Nitrogen Donor ◽  
Effect Of Oxygen ◽  
Donor Charge

Synthesis and vibrational spectra of tin(II) isothiocyanate adducts with some O- and N-donor ligands

1978 ◽  
Vol 56 (15) ◽  
pp. 2039-2041 ◽  
Author(s):  
Tewfik B. Absi ◽  
Ramesh C. Makhija ◽  
Mario Onyszchuk
Keyword(s):  
Molecular Weight ◽  
Powder Diffraction ◽  
Triphenylphosphine Oxide ◽  
Donor Ligands ◽  
Infrared And Raman Spectra ◽  
Powder Diffraction Data ◽  
Nitrogen Donor Ligands ◽  
X Ray ◽  
Oxygen Donor ◽  
Nitrogen Donor

Five new adducts of Sn(NCS)2 have been prepared and characterized: Sn(NCS)2•2L (L = 2,6-dimethyl-y-pyrone and N,N-dimethylacetamide), Sn(NCS)2•LL (LL = 1,10-phenanthroline and 2,2′-bipyridine), and Sn(NCS)(ox) (ox = 8-hydroxyquinolinate). By comparing their infrared and Raman spectra with those of SnX2•L (X = Cl, NCS; L = triphenylphosphine oxide), SnX2•2L (X = Cl, NCS; L = dimethylsulphoxide and pyridine-N-oxide), SnCl2•LL (LL = 1,10-phenanthroline and 2,2′-bipyridine), and SnCl(ox), assignments have been made for v(CN), v(CS), and δ(NCS) vibrations; these suggest the presence of N-bonded and —NCS— bridge-bonded thiocyanate groups. Molecular weight, conductivity, and X-ray powder diffraction data support the conclusion that the adducts with the oxygen donor ligands are molecular with only N-bonded thiocyanate groups. Adducts with the bidentate nitrogen donor ligands are polymeric and have —NCS— bridging and N-bonded thiocyanate.

Mössbauer and Related Studies of Complexes of R2 Sn(NCS)2 with Neutral Ligands Containing Oxygen Donor Atoms

1975 ◽  
Vol 53 (21) ◽  
pp. 3200-3205 ◽  
Author(s):  
F. Patricia Mullins ◽  
Columba Curran
Keyword(s):  
Donor Ligands ◽  
Type I ◽  
Bidentate Ligands ◽  
Nitrogen Donor Ligands ◽  
Oxygen Donor ◽  
Nitrogen Donor ◽  
Group A ◽  
Neutral Ligands ◽  
Monodentate Ligands ◽  
Oxygen Donors

Mössbauer, infrared, and electric dipole moment data are reported for several complexes of the type (i) R2Sn(NCS)2L2 and (ii) R2SnX2B (where R = C4H9, C2H3, C6H5; X = Cl, NCS; L = monodentate ligands with O, S donor atoms; B = bidentate ligands with O, P, As donor atoms). Quadrupole splittings indicate trans C—Sn—C bonds in octahedral complexes of divinyl-and diphenyltin diisothiocyanate with bidentate oxygen-donor ligands, in contrast to a cis configuration for complexes with bidentate nitrogen-donor ligands. Data indicate that the 1:2 complex of 2,2-bipyridyl-N,N′-dioxide with Bu2Sn(NCS)2 is polymeric, with octahedral monomer units having one bridging and one terminal NCS group, a bridging bipyO2 ligand and trans butyl groups. [Ph2Sn(NCS)2]2•bipyO2 appears to be a dimer with a bridging bipyO2 ligand and five-coordinate tin atoms. Mössbauer parameters for R2SnX2L2 and R2SnX2B complexes having oxygen donors are similar.

The role of zero-field splitting and π-stacking interaction of different nitrogen-donor ligands on the optical properties of luminescent rhenium tricarbonyl complexes

2021 ◽  
Author(s):  
Plinio Cantero-López ◽  
Yoan Hidalgo-Rosa ◽  
Zoraida Sandoval-Olivares ◽  
Julián Santoyo-Flores ◽  
Pablo Mella ◽  
...  
Keyword(s):  
Excited States ◽  
Coordination Compounds ◽  
Donor Ligands ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor ◽  
Π Stacking Interaction ◽  
Rhenium Tricarbonyl

Rhenium tricarbonyl complexes are one of the most important classes of coordination compounds in inorganic chemistry. Exploring their luminescent excited states, lowest singlet (S1), and the lowest triplet (T1), is...

scholarly journals New Synthetic Routes Toward Enantiopure Nitrogen Donor Ligands.

ChemInform ◽  
2007 ◽  
Vol 38 (15) ◽  
Author(s):  
Xavier Sala ◽  
Anna M. Rodriguez ◽  
Montserrat Rodriguez ◽  
Isabel Romero ◽  
Teodor Parella ◽  
...  
Keyword(s):  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor ◽  
Synthetic Routes

Oxidative Degradation of Toxic Organic Pollutants by Water Soluble Nonheme Iron(IV)-Oxo Complexes of Polydentate Nitrogen Donor Ligands

2021 ◽  
Author(s):  
Sandip Munshi ◽  
Rahul Dev Jana ◽  
Tapan Kanti Paine
Keyword(s):  
Organic Pollutants ◽  
Oxidative Degradation ◽  
Heme Iron ◽  
Water Soluble ◽  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Polydentate Ligands ◽  
Oxo Complexes ◽  
Non Heme Iron ◽  
Nitrogen Donor

The ability of four mononuclear non-heme iron(IV)-oxo complexes supported by nitrogen donor polydentate ligands in degrading organic pollutants has been investigated. The water soluble iron(II) complexes upon treatment with ceric...

NiII formate complexes with bi- and tridentate nitrogen-donor ligands: synthesis, characterization, and magnetic and thermal properties

2017 ◽  
Vol 46 (12) ◽  
pp. 3963-3979 ◽  
Author(s):  
Karoline Rühlig ◽  
Akerke Abylaikhan ◽  
Azar Aliabadi ◽  
Vladislav Kataev ◽  
Simon Liebing ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Metallic Nickel ◽  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor

New NiII formate complexes were synthesized and characterized to exhibit low decomposition temperatures to produce pure metallic nickel.

Adduct Formation of Dichloridodioxidomolybdenum(VI) and Methyltrioxidorhenium(VII) with a Series of Bidentate Nitrogen Donor Ligands

2009 ◽  
Vol 2009 (8) ◽  
pp. 1019-1026 ◽  
Author(s):  
Ahmad M. Al-Ajlouni ◽  
Alev Günyar ◽  
Ming-Dong Zhou ◽  
Paul N. W. Baxter ◽  
Fritz E. Kühn
Keyword(s):  
Adduct Formation ◽  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor

Mono- and polynuclear rhodium(I) complexes with nitrogen-donor ligands

1981 ◽  
Vol 220 (1) ◽  
pp. 103-113 ◽  
Author(s):  
R. Usón ◽  
L.A. Oro ◽  
D. Carmona ◽  
M. Esteban
Keyword(s):  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Nitrogen Donor
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