Calorimetric Determination of the Formation Enthalpies of Cs Polymolybdates at 298.15 K and 0.1 MPa

2020 ◽  
Vol 65 (8) ◽  
pp. 3875-3883 ◽  
Author(s):  
Pierre Benigni ◽  
Georges Mikaelian ◽  
Elise Ruiz ◽  
Carine Perrin-Pellegrino ◽  
Jacques Rogez
1973 ◽  
Vol 28 (9-10) ◽  
pp. 533-554 ◽  
Author(s):  
Lothar Rafflenbeul ◽  
Wa-Ming Pang ◽  
Hansjürgen Schönert ◽  
Klaus Haberle

Abstract Isopiestic vapor pressure measurements and calorimetric determination of the heat of dilution have been performed and evaluated with respect to enthalpy, entropy and free enthalpy in the ternary solutions water+ glycin+ urea and water+ alanin + urea. The free enthalpy of transfer for the process: Amino acid from water to water+ urea, which can be derived from these measurements, does not agree with the value calculated from solubility measurements. The reason for this discrepancy and the values of entropy and enthalpy in terms of hydrophobic interaction are discussed. Supplementary measurements of the proton magnetic resonance in these solutions are included.


2014 ◽  
Vol 37 (6) ◽  
Author(s):  
Zeming Chen ◽  
Zijing Li ◽  
Yaqi Zhang ◽  
Riping Liu ◽  
Yongjun Tian ◽  
...  

1992 ◽  
Vol 139 (10) ◽  
pp. 2755-2759
Author(s):  
E. E. Kalu ◽  
R. E. White ◽  
E. C. Darcy

2013 ◽  
Vol 67 (2) ◽  
Author(s):  
Pavel Šiler ◽  
Josef Krátký ◽  
Iva Kolářová ◽  
Jaromír Havlica ◽  
Jiří Brandštetr

AbstractPossibilities of a multicell isoperibolic-semiadiabatic calorimeter application for the measurement of hydration heat and maximum temperature reached in mixtures of various compositions during their setting and early stages of hardening are presented. Measurements were aimed to determine the impact of selected components’ content on the course of ordinary Portland cement (OPC) hydration. The following components were selected for the determination of the hydration behaviour in mixtures: very finely ground granulated blast furnace slag (GBFS), silica fume (microsilica, SF), finely ground quartz sand (FGQ), and calcined bauxite (CB). A commercial polycarboxylate type superplasticizer was also added to the selected mixtures. All maximum temperatures measured for selected mineral components were lower than that reached for cement. The maximum temperature increased with the decreasing amount of components in the mixture for all components except for silica fume. For all components, except for CB, the values of total released heat were higher than those for pure Portland cement samples.


Soil Science ◽  
1963 ◽  
Vol 95 (6) ◽  
pp. 376-384 ◽  
Author(s):  
JACK H. KOLAIAN ◽  
PHILIP F. LOW

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