Solvatochromism of Binary Mixtures of 2,2,2-Trifluoroethanol + Ionic Liquid [bmim][Tf2N]: A Comparative Study with Molecular Solvents

2019 ◽  
Vol 64 (3) ◽  
pp. 1140-1154 ◽  
Author(s):  
Md Rabiul Islam ◽  
Faiz Warsi ◽  
Abbul Bashar Khan ◽  
Tasneem Kausar ◽  
Imran Khan ◽  
...  
2015 ◽  
Vol 119 (2) ◽  
pp. 543-551 ◽  
Author(s):  
Kamil Paduszyński ◽  
Elena Vadimovna Lukoshko ◽  
Marek Królikowski ◽  
Urszula Domańska ◽  
Jerzy Szydłowski

2008 ◽  
Vol 140 (3) ◽  
pp. 329-334 ◽  
Author(s):  
Mohammad Khodadadi-Moghaddam ◽  
Aziz Habibi-Yangjeh ◽  
Mohamad Reza Gholami

2020 ◽  
Vol 22 (19) ◽  
pp. 10995-11011 ◽  
Author(s):  
Dilek Yalcin ◽  
Andrew J. Christofferson ◽  
Calum J. Drummond ◽  
Tamar L. Greaves

In this study, we have investigated the solvation properties of binary mixtures of PILs with molecular solvents. The selected binary solvent systems are the PILs ethylammonium nitrate (EAN) and propylammonium nitrate (PAN) combined with either water, methanol, acetonitrile or DMSO.


2013 ◽  
Vol 25 (2) ◽  
pp. 146-158 ◽  
Author(s):  
Kumkum Ahmed ◽  
Anika Auni ◽  
Gulshan Ara ◽  
MM Rahman ◽  
M Yousuf Aa Mollah ◽  
...  

Polarity behavior of a hydrophobic ionic liquid (IL) 1-ethyl-3-methylimidazolium bis(trifluoromethyl)sulphonylimide [EMI][TFSI] and binary mixtures of [EMI][TFSI] with ethanol, acetone and dichloromethane was investigated by solvatochromic method using Reichardt’s betaine dye. Fluorescence spectroscopic method using pyrene as a probe was also used for estimation of polarity of [EMI][TFSI] and [EMI][TFSI]-based binary systems. The binary mixtures of [EMI][TFSI] with the molecular solvents interestingly showed increase in polarity with increasing [EMI][TFSI] for all compositions. The comparative and contrastive features of the results of two methods have been discussed to judge relative merit of one method over the other. Both of the methods collectively provided information to correlate specific interaction of the IL with molecular solvents and define polarity behavior. Journal of Bangladesh Chemical Society, Vol. 25(2), 146-158, 2012 DOI: http://dx.doi.org/10.3329/jbcs.v25i2.15067


2019 ◽  
Vol 16 (7) ◽  
pp. 550-555
Author(s):  
Dinesh K. Jangid ◽  
Keshav L. Ameta ◽  
Surbhi Dhadda ◽  
Anjali Guleria ◽  
Prakash G. Goswami ◽  
...  

Ionic Liquid assisted efficient synthesis of some 2-aminobenzenethiols has been reported using three different Ionic Liquids (ILs) namely methylimidazolium tetrafluoroborate [MIM]+[BF4]−, methylimidazolium chloride [MIM]+[Cl]− and methylimidazolium nitrate [MIM]+[NO3]−. A comparative study has been carried out for the synthesis of target molecules in the presence and absence of IL, leading to conclusion that maximum yield has been observed with [MIM]+[BF4]−.


2017 ◽  
Vol 5 (4) ◽  
pp. 3429-3437 ◽  
Author(s):  
Alsu I. Akhmetshina ◽  
Anton N. Petukhov ◽  
Andrey V. Vorotyntsev ◽  
Alexander V. Nyuchev ◽  
Ilya V. Vorotyntsev

2009 ◽  
Vol 113 (5) ◽  
pp. 1429-1437 ◽  
Author(s):  
Peter Nockemann ◽  
Koen Binnemans ◽  
Ben Thijs ◽  
Tatjana N. Parac-Vogt ◽  
Klaus Merz ◽  
...  
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