Synthetic Scope of Brønsted Acid-Catalyzed Reactions of Carbonyl Compounds and Ethyl Diazoacetate

Author(s):  
Mizzanoor Rahaman ◽  
M. Shahnawaz Ali ◽  
Khorshada Jahan ◽  
Damon Hinz ◽  
Jawad Bin Belayet ◽  
...  
2020 ◽  
Vol 56 (61) ◽  
pp. 8691-8694
Author(s):  
Mohanad A. Hussein ◽  
An H. Dinh ◽  
Vien T. Huynh ◽  
Thanh Vinh Nguyen

Triflic acid efficiently promotes the reductive amination reactions of carbonyl compounds on a broad range of substrates.


2017 ◽  
Vol 15 (4) ◽  
pp. 863-869 ◽  
Author(s):  
Suleman M. Inamdar ◽  
Rajesh G. Gonnade ◽  
Nitin T. Patil

A general method to access annulated bis-indoles from (1H-indol-3-yl)(aryl)methanols and 2-(arylethynyl)-1H-indoles under the catalysis of the Ph3PAuOTf/Brønsted acid binary catalyst system has been developed.


2020 ◽  
Vol 26 (48) ◽  
pp. 10976-10980 ◽  
Author(s):  
Joel J. Montalvo‐Acosta ◽  
Marian Dryzhakov ◽  
Edward Richmond ◽  
Marco Cecchini ◽  
Joseph Moran

Synthesis ◽  
2018 ◽  
Vol 50 (10) ◽  
pp. 1935-1957 ◽  
Author(s):  
Daniel Sedgwick ◽  
Matthew Grayson ◽  
Santos Fustero ◽  
Pablo Barrio

The 50-year-old allylboration reaction has seen dramatic developments since the dawn of the new century after the first catalytic asymmetric versions came into play. In the past decade alone, several methodologies capable of achieving the desired homoallylic alcohols in over 90% ee have been developed. This review focuses on the chiral Brønsted acid catalyzed allylboration reaction, covering everything from the very first examples and precedents to modern day variations and applications.1 Introduction2 Early Developments3 Synthetic Applications4 Variants5 Computational Contribution6 Conclusions


Synthesis ◽  
2016 ◽  
Vol 48 (24) ◽  
pp. 4525-4532 ◽  
Author(s):  
Valerij Nikolaev ◽  
Jury Medvedev ◽  
Dmitrii Semenok ◽  
Xenia Azarova ◽  
Liudmila Rodina

2015 ◽  
Vol 51 (5) ◽  
pp. 903-906 ◽  
Author(s):  
Shengzong Liang ◽  
Gerald B. Hammond ◽  
Bo Xu

The combined acid catalyzed hydration of alkynes is an efficient one-step synthesis of carbonyl compounds.


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