Ultrafast Charge Transfer and Relaxation at a Donor–Acceptor Interface

Author(s):  
Fernando Rodríguez Díaz ◽  
Hong-Guang Duan ◽  
R. J. Dwayne Miller ◽  
Michael Thorwart
2018 ◽  
Vol 54 (6) ◽  
pp. 666-669
Author(s):  
Hucheng Zhang ◽  
Mengmeng Wang ◽  
Jing Zhao ◽  
Shitao Han ◽  
Haixia Cheng ◽  
...  

The charge transfer and active sites of metal-free imidazolium-based composites were unveiled by an electrochemical method with high sensitivity and selectivity due to the specific donor–acceptor coupling of imidazolium with NO2−.


1994 ◽  
Vol 100 (7) ◽  
pp. 4797-4810 ◽  
Author(s):  
Klaas Wynne ◽  
C. Galli ◽  
R. M. Hochstrasser

Author(s):  
Valentina A. Mikhailova ◽  
Sergey V. Feskov ◽  
Vladimir N. Ionkin ◽  
Vladislav V. Yudanov ◽  
Anatoly I. Ivanov

2021 ◽  
Vol 494 ◽  
pp. 229710
Author(s):  
Takashi Teranishi ◽  
Kaisei Kozai ◽  
Sou Yasuhara ◽  
Shintaro Yasui ◽  
Naoyuki Ishida ◽  
...  

2021 ◽  
Vol 7 (9) ◽  
pp. eabd9061
Author(s):  
Shuai Fu ◽  
Indy du Fossé ◽  
Xiaoyu Jia ◽  
Jingyin Xu ◽  
Xiaoqing Yu ◽  
...  

Van der Waals heterostructures consisting of graphene and transition metal dichalcogenides have shown great promise for optoelectronic applications. However, an in-depth understanding of the critical processes for device operation, namely, interfacial charge transfer (CT) and recombination, has so far remained elusive. Here, we investigate these processes in graphene-WS2 heterostructures by complementarily probing the ultrafast terahertz photoconductivity in graphene and the transient absorption dynamics in WS2 following photoexcitation. We observe that separated charges in the heterostructure following CT live extremely long: beyond 1 ns, in contrast to ~1 ps charge separation reported in previous studies. This leads to efficient photogating of graphene. Furthermore, for the CT process across graphene-WS2 interfaces, we find that it occurs via photo-thermionic emission for sub-A-exciton excitations and direct hole transfer from WS2 to the valence band of graphene for above-A-exciton excitations. These findings provide insights to further optimize the performance of optoelectronic devices, in particular photodetection.


2016 ◽  
Vol 145 (24) ◽  
pp. 244705 ◽  
Author(s):  
Shuang-Bao Li ◽  
Yun Geng ◽  
Yu-Ai Duan ◽  
Guang-Yan Sun ◽  
Min Zhang ◽  
...  

2D Materials ◽  
2016 ◽  
Vol 3 (2) ◽  
pp. 025020 ◽  
Author(s):  
Bo Peng ◽  
Guannan Yu ◽  
Xinfeng Liu ◽  
Bo Liu ◽  
Xiao Liang ◽  
...  

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