On the Different Faces of the Supercritical Phase of Water at a Near-Critical Temperature: Pressure-Induced Structural Transitions Ranging from a Gaslike Fluid to a Plastic Crystal Polymorph

2021 ◽  
Author(s):  
Ioannis Skarmoutsos ◽  
Andrés Henao ◽  
Elvira Guardia ◽  
Jannis Samios
Keyword(s):  
Critical Temperature ◽  
Plastic Crystal ◽  
Structural Transitions ◽  
Supercritical Phase

Optical properties of the Vanadium dioxide

2015 ◽  
Vol 8 (2) ◽  
pp. 2148-2155 ◽  
Author(s):  
Abderrahim Benchaib ◽  
Abdesselam Mdaa ◽  
Izeddine Zorkani ◽  
Anouar Jorio
Keyword(s):  
Energy Efficiency ◽  
Optical Properties ◽  
Critical Temperature ◽  
Thin Layer ◽  
Dielectric Function ◽  
Vanadium Dioxide ◽  
Ultra Violet ◽  
Index Of Refraction ◽  
Practical Utility ◽  
Infra Red

The vanadium dioxide is a material thermo chromium which sees its optical properties changing at the time of the transition from the phase of semiconductor state ↔ metal, at a critical temperature of 68°C. The study of the optical properties of a thin layer of VO₂ thickness 82 nm, such as the dielectric function, the index of refraction, the coefficient ofextinction, the absorption’s coefficient, the reflectivity, the transmittivity, in the photonic spectrum of energy ω located inthe interval: 0.001242 ≤ ω (ev) ≤ 6, enables us to control well its practical utility in various applications, like the intelligentpanes, the photovoltaic, paintings for increasing energy efficiency in buildings, detectors of infra-red (I.R) or ultra-violet(U.V). We will make simulations with Maple and compare our results with those of the literature

Two-Dimensional Infrared Spectroscopy From the Gas to Liquid Phase: Density Dependent J-Scrambling, Vibrational Relaxation, and the Onset of Liquid Character

2019 ◽  
Author(s):  
Greg Ng Pack ◽  
Matthew Rotondaro ◽  
Parth Shah ◽  
Aritra Mandal ◽  
Shyamsunder Erramilli ◽  
...  
Keyword(s):  
Vibrational Energy ◽  
Rotational Relaxation ◽  
Vibrational Energy Relaxation ◽  
Pump Probe ◽  
Solution Dynamics ◽  
Supercritical Phase ◽  
Supercritical Solution ◽  
Asymmetric Stretch ◽  
Two Dimensional Infrared Spectroscopy ◽  
Vibrational Equilibrium

Ultrafast 2DIR spectra and pump-probe responses of the N2O n 3 asymmetric stretch in SF6 as a function of density from the gas to supercritical phase and liquid are reported. 2DIR spectra unequivocally reveal free rotor character at all densities studied in the gas and supercritical region. Analysis of the 2DIR spectra determines that J-scrambling or rotational relaxation in N2O is highly efficient, occurring in ~1.5 to ~2 collisions with SF6 at all non-liquid densities. In contrast, N2O n 3 vibrational energy relaxation requires ~15 collisions, and complete vibrational equilibrium occurs on the ~ns scale at all densities. An independent binary collision model is sufficient to describe these supercritical state point dynamics. The N2O n 3 in liquid SF6 2DIR spectrum shows no evidence of free rotor character or spectral diffusion. Using these 2DIR results, hindered rotor or liquid-like character is found in gas and all supercritical solutions for SF6 densities ³ r * = 0.3, and increases with SF6 density. 2DIR spectral analysis offers direct time domain evidence of critical slowing for SF6 solutions closest to the critical point density. Applications of 2DIR to other high density and supercritical solution dynamics and descriptions are discussed. <br>

ALLEGHENY STAINLESS TYPE 405

Alloy Digest ◽  
1985 ◽  
Vol 34 (7) ◽  
Keyword(s):  
Fracture Toughness ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Critical Temperature ◽  
Physical Properties ◽  
Tensile Properties ◽  
Heat Treating ◽  
Ductile Material ◽  
Air Cooling ◽  
Temperature Performance

Abstract ALLEGHENY STAINLESS Type 405, unlike most other 12% chromium steels, is not subject to appreciable hardening through air cooling from high temperatures. This is an advantageous characteristic in those applications where a soft, ductile material is required after rapid cooling from above the critical temperature. The nonhardening tendency of Type 405 also retards the formation of hardening cracks where welding is employed. Its uses include annealing boxes and baffles where hardening during cooling would be undesirable. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on high temperature performance and corrosion resistance as well as heat treating and machining. Filing Code: SS-461. Producer or source: Allegheny Ludlum Corporation.

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